Tetraaminophenazine‐Derived Redox‐Active Coordination Polymer for Lithium‐Ion Batteries

Herein, we report the synthesis of a nickel(II) coordination polymer P1, derived from a tetraaminophenazine ligand, and its evaluation as cathode material for lithium batteries. The P1 ‐based batteries demonstrated long‐term operational stability for over 1800 cycles at a high current density of 1 A g −1 and delivered remarkable specific discharge capacity of ca. 160 mAh g −1 . Ex situ Fourier‐transform infrared spectroscopy study unraveled the electrode degradation pathways realized upon the battery cycling.

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Journal
physica status solidi (a)
Published
2026-02-17
DOI
https://doi.org/10.1002/pssa.202500999
Primary Topic
Advancements in Battery Materials
Type
article
Field-Weighted Citation Impact
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article

Tetraaminophenazine‐Derived Redox‐Active Coordination Polymer for Lithium‐Ion Batteries

Tatiana A. Savinykh, Kraevaya OA, N H Dremova, Alexander V. Mumyatov et al.
physica status solidi (a)
Advancements in Battery Materials
article

Tetraaminophenazine‐Derived Redox‐Active Coordination Polymer for Lithium‐Ion Batteries

Tatiana A. Savinykh, Kraevaya OA, N H Dremova, Alexander V. Mumyatov, Екатерина А. Комиссарова, Pavel A. Troshin, Andrey I. Kukharenko, Ivan S. Zhidkov, Sergey Aldoshin, Sergey G. Vasiliev, Polina D. Orlova
article en

Abstract

Herein, we report the synthesis of a nickel(II) coordination polymer P1, derived from a tetraaminophenazine ligand, and its evaluation as cathode material for lithium batteries. The P1 ‐based batteries demonstrated long‐term operational stability for over 1800 cycles at a high current density of 1 A g −1 and delivered remarkable specific discharge capacity of ca. 160 mAh g −1 . Ex situ Fourier‐transform infrared spectroscopy study unraveled the electrode degradation pathways realized upon the battery cycling.

physica status solidi (a)Vol. 223(4)
Ural Federal University (RU), Lomonosov Moscow State University (RU), Henan Institute of Education (CN), M.N. Mikheev Institute of Metal Physics (RU), Institute of Problems of Chemical Physics (RU), Henan Communication Science and Technology Research Institute (China) (CN), Moscow State University (TJ), Zhengzhou Institute of Machinery (CN)
Openalex Percentile: Top 53%
Advancements in Battery Materials
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Tetraaminophenazine‐Derived Redox‐Active Coordination Polymer for Lithium‐Ion Batteries — Tatiana A. Savinykh, Kraevaya OA, et al. · physica status solidi (a) (2026) | TGRS Research Map | TGRS