Integrating Experimental Crystallization Kinetics into Autodesk Moldflow: Validation and Crystallinity Prediction for iPP and POM

An accurate prediction of the final properties of injection-molded semi-crystalline parts requires models that capture crystallization kinetics during processing. This work presents two practical strategies to incorporate experimentally derived crystallization behaviors into Autodesk Moldflow, addressing cases where kinetics differ from the software's native Avrami-Hoffman-Lauritzen formulation. We apply these methods to isotactic polypropylene (iPP T30G) displaying heterogeneous nucleation with a low-temperature plateau, and to polyoxymethylene (POM) exhibiting combined heterogeneous and homogeneous nucleation. The parameters for Moldflow were obtained by matching isothermal half-crystallization times (t<sub>0.5</sub>) and by tuning flow-induced nucleation terms. Validation against isothermal and non-isothermal injection tests shows agreement between calculated and expected crystallinity evolution and reproduces measured spherulite diameters.

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Publication Details

Journal
Polymers
Published
2026-02-14
DOI
https://doi.org/10.3390/polym18040482
Primary Topic
Polymer crystallization and properties
Type
article
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article

Integrating Experimental Crystallization Kinetics into Autodesk Moldflow: Validation and Crystallinity Prediction for iPP and POM

Valentina Volpe, Rita Salomone, Vito Speranza, Roberto Pantani
Polymers
Polymer crystallization and properties
article

Integrating Experimental Crystallization Kinetics into Autodesk Moldflow: Validation and Crystallinity Prediction for iPP and POM

Valentina Volpe, Rita Salomone, Vito Speranza, Roberto Pantani
article en

Abstract

An accurate prediction of the final properties of injection-molded semi-crystalline parts requires models that capture crystallization kinetics during processing. This work presents two practical strategies to incorporate experimentally derived crystallization behaviors into Autodesk Moldflow, addressing cases where kinetics differ from the software's native Avrami-Hoffman-Lauritzen formulation. We apply these methods to isotactic polypropylene (iPP T30G) displaying heterogeneous nucleation with a low-temperature plateau, and to polyoxymethylene (POM) exhibiting combined heterogeneous and homogeneous nucleation. The parameters for Moldflow were obtained by matching isothermal half-crystallization times (t<sub>0.5</sub>) and by tuning flow-induced nucleation terms. Validation against isothermal and non-isothermal injection tests shows agreement between calculated and expected crystallinity evolution and reproduces measured spherulite diameters.

PolymersVol. 18(4)
University of Salerno (IT)
Openalex Percentile: Top 56%
Polymer crystallization and properties
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Integrating Experimental Crystallization Kinetics into Autodesk Moldflow: Validation and Crystallinity Prediction for iPP and POM — Valentina Volpe, Rita Salomone, et al. · Polymers (2026) | TGRS Research Map | TGRS