Aqua(ethanol-κ <i>O</i> )tris[4,4,4-trifluoro-1-(4-propoxyphenyl)butane-1,3-dionato(1−)-κ <sup>2</sup> <i>O</i> , <i>O</i> ′]europium(III)

In the title compound, [Eu(C<sub>13</sub>H<sub>12</sub>F<sub>3</sub>O<sub>3</sub>)<sub>3</sub>(C<sub>2</sub>H<sub>5</sub>OH)(H<sub>2</sub>O)], the tris-[4,4,4-tri-fluoro-1-(4-propoxyphen-yl)butane-1,3-dionato(1-)]europium(III) complex is augmented by ethanol and water mol-ecules as neutral co-ligands, leading to a coordination number of 8 of the central Eu<sup>III</sup> ion. In the crystal structure, O-H⋯O hydrogen bonding involving ethanol and water as donor and meth-oxy O atoms as acceptor groups consolidates the crystal packing. The complex has been characterized by positive ion FAB-MS and luminescence spectroscopy.

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Publication Details

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IUCrData
Published
2026-02-11
DOI
https://doi.org/10.1107/s2414314626001380
Primary Topic
Lanthanide and Transition Metal Complexes
Type
article
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Aqua(ethanol-κ O )tris[4,4,4-trifluoro-1-(4-propoxyphenyl)butane-1,3-dionato(1−)-κ 2 O , O ′]europium(III)

Misa Sasaki, Tetsuji Moriguchi, Noriko Miyoshi
IUCrData
Lanthanide and Transition Metal Complexes
article

Aqua(ethanol-κ O )tris[4,4,4-trifluoro-1-(4-propoxyphenyl)butane-1,3-dionato(1−)-κ 2 O , O ′]europium(III)

Misa Sasaki, Tetsuji Moriguchi, Noriko Miyoshi
article en

Abstract

In the title compound, [Eu(C<sub>13</sub>H<sub>12</sub>F<sub>3</sub>O<sub>3</sub>)<sub>3</sub>(C<sub>2</sub>H<sub>5</sub>OH)(H<sub>2</sub>O)], the tris-[4,4,4-tri-fluoro-1-(4-propoxyphen-yl)butane-1,3-dionato(1-)]europium(III) complex is augmented by ethanol and water mol-ecules as neutral co-ligands, leading to a coordination number of 8 of the central Eu<sup>III</sup> ion. In the crystal structure, O-H⋯O hydrogen bonding involving ethanol and water as donor and meth-oxy O atoms as acceptor groups consolidates the crystal packing. The complex has been characterized by positive ion FAB-MS and luminescence spectroscopy.

IUCrDataVol. 11(2)
Kyushu Institute of Technology (JP)
Clean water and sanitation
Openalex Percentile: Top 58%
Lanthanide and Transition Metal Complexes
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