Landé factors for selected levels of the e <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si103.svg" display="inline" id="d1e2126"> <mml:mrow> <mml:msup> <mml:mrow/> <mml:mrow> <mml:mn>6</mml:mn> </mml:mrow> </mml:msup> <mml:mi math

We investigate the Zeeman effect in the 0-0 band of the e 6 Π –a 6 Δ system of FeH, producing the molecule at near-ambient temperatures and recording Doppler-limited laser excitation spectra, using selective detection. We provide a set of effective Landé factors for the three lowest spin components of both states, extracted from the analysis of partially-resolved Zeeman patterns seen in magnetic flux denisities of 0.4 –0.7 T. Landé factors in the upper state show strong variations with parity, unlike the lower state level, which is close to having a single electronic configuration. Landé factors for two Fe(I) lines at 18611.635 cm − 1 and 19573.056 cm − 1 , recorded for magnetic flux density calibration, have been refined in the process. • Laser excitation spectra were collected from selected e 6 Π - a 6 Δ transitions of FeH in the presence of an applied magnetic flux density. • Landé factors for the associated rotational levels were obtained. • A perturbation in one spectrum was tentatively attributed to a Zeeman-induced interaction between the a 6 Δ 9/2 v=0 J=6.5 and X 4 Δ 7/2 v=1 J=7.5 levels. • Landé factors for three levels of atomic iron were improved.

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Publication Details

Journal
Journal of Molecular Spectroscopy
Published
2026-02-01
DOI
https://doi.org/10.1016/j.jms.2026.112081
Citations
1
Primary Topic
Magnetism in coordination complexes
Type
article
Field-Weighted Citation Impact
11.44
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Landé factors for selected levels of the e <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si103.svg" display="inline" id="d1e2126"> <mml:mrow> <mml:msup> <mml:mrow/> <mml:mrow> <mml:mn>6</mml:mn> </mml:mrow> </mml:msup> <mml:mi math

A.J. Ross, A.G. Adam, D.W. Tokaryk, P. Crozet et al.
1 citations
Journal of Molecular Spectroscopy
Magnetism in coordination complexes
11.44
article

Landé factors for selected levels of the e <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si103.svg" display="inline" id="d1e2126"> <mml:mrow> <mml:msup> <mml:mrow/> <mml:mrow> <mml:mn>6</mml:mn> </mml:mrow> </mml:msup> <mml:mi math

A.J. Ross, A.G. Adam, D.W. Tokaryk, P. Crozet, T.E. Blackmore
article en
1 citations

Abstract

We investigate the Zeeman effect in the 0-0 band of the e 6 Π –a 6 Δ system of FeH, producing the molecule at near-ambient temperatures and recording Doppler-limited laser excitation spectra, using selective detection. We provide a set of effective Landé factors for the three lowest spin components of both states, extracted from the analysis of partially-resolved Zeeman patterns seen in magnetic flux denisities of 0.4 –0.7 T. Landé factors in the upper state show strong variations with parity, unlike the lower state level, which is close to having a single electronic configuration. Landé factors for two Fe(I) lines at 18611.635 cm − 1 and 19573.056 cm − 1 , recorded for magnetic flux density calibration, have been refined in the process. • Laser excitation spectra were collected from selected e 6 Π - a 6 Δ transitions of FeH in the presence of an applied magnetic flux density. • Landé factors for the associated rotational levels were obtained. • A perturbation in one spectrum was tentatively attributed to a Zeeman-induced interaction between the a 6 Δ 9/2 v=0 J=6.5 and X 4 Δ 7/2 v=1 J=7.5 levels. • Landé factors for three levels of atomic iron were improved.

Journal of Molecular SpectroscopyVol. 416-417
Université Claude Bernard Lyon 1 (FR), University of New Brunswick (CA), Centre National de la Recherche Scientifique (FR), Institut Lumière Matière (FR)
Openalex Percentile: Top 2%
Magnetism in coordination complexes
11.44
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Landé factors for selected levels of the e <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si103.svg" display="inline" id="d1e2126"> <mml:mrow> <mml:msup> <mml:mrow/> <mml:mrow> <mml:mn>6</mml:mn> </mml:mrow> </mml:msup> <mml:mi math — A.J. Ross, A.G. Adam, et al. · Journal of Molecular Spectroscopy (2026) | TGRS Research Map | TGRS