Effect of Application Method and Amount of Expandable Graphite with Polyurea on Wood Thermal Resistance

Wood, which is flammable, is commonly used as a building material and can be improved using a suitable surface treatment. A promising coating solution is polyurea, featuring properties like flexibility, mechanical resistance, resistance against water, etc., but it is also easily flammable. Expandable graphite (EG) is effective as a flame retardant and environmentally suitable. In this study, we studied the suitability of polyurea improved with EG. Spruce wood samples with dimensions of 50 mm × 40 mm × 10 mm were divided into eight groups, each including five samples. Each group was subjected to two applications of polyurea and EG in various combinations to examine the best combination with the lowest mass loss. The second component of the experiments aimed to examine the effectiveness of EG, which was applied in different weights. During the experiments, samples were thermally loaded in an apparatus for 10 min, where a heat flux of 30 kW·m−2 was applied to the sample surface and the mass loss was continuously recorded. Lastly, thermal analysis was performed. The best results were observed for the combination of NEOPROOF mixed with 0.3 g of EG covered with NEODUR. The thermal analysis results revealed substantial differences: NEOPROOF, a polyurea, had only one degradation step, while NEODUR, which also contained polyurethanes, decomposed in several steps.

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Publication Details

Journal
Coatings
Published
2026-02-12
DOI
https://doi.org/10.3390/coatings16020231
Primary Topic
Flame retardant materials and properties
Type
article
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article

Effect of Application Method and Amount of Expandable Graphite with Polyurea on Wood Thermal Resistance

Adriana Eštoková, Elena V. Kmetova, Danica Kačíková, František Kacík et al.
Coatings
Flame retardant materials and properties
article

Effect of Application Method and Amount of Expandable Graphite with Polyurea on Wood Thermal Resistance

Adriana Eštoková, Elena V. Kmetova, Danica Kačíková, František Kacík, Katarína Trojanová
article en

Abstract

Wood, which is flammable, is commonly used as a building material and can be improved using a suitable surface treatment. A promising coating solution is polyurea, featuring properties like flexibility, mechanical resistance, resistance against water, etc., but it is also easily flammable. Expandable graphite (EG) is effective as a flame retardant and environmentally suitable. In this study, we studied the suitability of polyurea improved with EG. Spruce wood samples with dimensions of 50 mm × 40 mm × 10 mm were divided into eight groups, each including five samples. Each group was subjected to two applications of polyurea and EG in various combinations to examine the best combination with the lowest mass loss. The second component of the experiments aimed to examine the effectiveness of EG, which was applied in different weights. During the experiments, samples were thermally loaded in an apparatus for 10 min, where a heat flux of 30 kW·m−2 was applied to the sample surface and the mass loss was continuously recorded. Lastly, thermal analysis was performed. The best results were observed for the combination of NEOPROOF mixed with 0.3 g of EG covered with NEODUR. The thermal analysis results revealed substantial differences: NEOPROOF, a polyurea, had only one degradation step, while NEODUR, which also contained polyurethanes, decomposed in several steps.

CoatingsVol. 16(2)
Technical University of Košice (SK), Technická univerzita vo Zvolene (SK)
Openalex Percentile: Top 58%
Flame retardant materials and properties
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