Diisopropyl(6-(phenyl(phenylthio)arsaneyl)-1,2-dihydroacenaphthylen-5-yl)phosphane
Peri-substituted bis(tertiary) phosphine-arsine Acenap(PiPr2)(As(SPh)Ph) (4, Acenap = acenaphthene-5,6-diyl) was synthesized by the reaction of the chloroarsine (PiPr2)(AsPhCl) with PhSLi. The X-ray crystal structure of this compound reveals an intramolecular P∙∙∙As–Cl pnictogen bond, with the phosphorus lone pair donating into the As–S σ* orbital.
Authors
- Lloyd J. Taylor
- Philip M. Pickett
- Petr Kilián (ORCID: https://orcid.org/0000-0001-6379-3026)
- David B. Cordes
Institutions
- University of St Andrews (GB)
Publication Details
- Journal
- Molbank
- Published
- 2026-02-10
- DOI
- https://doi.org/10.3390/m2139
- Primary Topic
- Synthesis and characterization of novel inorganic/organometallic compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00