Toward Reliable Triboelectric Nanogenerators: Roles of Lubricants

Triboelectric nanogenerators (TENGs) are a newly adopted technology designed to harvest freely available mechanical energy from the environment and convert it into electricity that can help to meet future demands for clean and sustainable energy. TENGs represent a promising next-generation renewable energy technology, an alternative to traditional non-renewable fossil fuel sources, with a wide range of applications, including smart sensors, wearable devices, internet of things (IoT), and portable electronics. Through contact/triboelectrification and electrostatic induction, TENGs convert mechanical energy into electrical energy. Broadly, TENGs are classified into contact–separation mode and sliding mode. In contact–separation mode, the electric output is achieved through the contact and separation of triboelectric layers, while in the sliding mode, it is generated by the sliding of one triboelectric layer over another. Sliding-mode TENGs have demonstrated better electrical output compared to the contact–separation mode; however, they suffer low durability and cannot operate for long periods due to severe wear. In addition, their electrical output performance is reduced owing to air breakdown. Lubricants have demonstrated their potential in TENGs by overcoming these limitations and improving both tribological and triboelectric performance. This review provides a discussion on the fundamental modes of TENGs, followed by a comprehensive summary of the tribological and triboelectrical performance of existing TENGs under liquid lubrication, along with a comparison of their performance under dry conditions. The effects of load, frequency, mass fraction, and volume of the liquid lubricant on both tribology and electrical output are examined. Durability is identified as a key factor for the long-term practical application of TENGs; hence, this paper also focuses on it. Furthermore, strategies for improving TENG performance and the working mechanisms under liquid lubrication are discussed. Finally, the paper summarizes demonstrations of TENG applications based on various TENG designs.