Photochemical Cyclization of N-Allyl-N-(2-formylphenyl)-4-methylbenzenesulfonamide
Abstract Photochemical cyclization of N -allyl- N -(2-formylphenyl)-4-methylbenzenesulfonamide in DMSO under irradiation with a light-emitting diode at λ 365 nm afforded 29% of 3-(4-methylbenzenesulfonyl)-1,1a,2,3-tetrahydro-7b H -cyclopropa[ c ]quinolin-7b-ol. The reaction is diastereoselective, and it requires no catalysis.
Authors
- M. S. Baranov
- A. Yu. Smirnov
- A. A. Korlyukov
- D. I. Rudik
- A. R. Romanenko
Institutions
- A. N. Nesmeyanov Institute of Organoelement Compounds (RU)
- Pirogov Russian National Research Medical University (RU)
- Institute of Bioorganic Chemistry (RU)
Publication Details
- Journal
- Russian Journal of Organic Chemistry
- Published
- 2025-12-01
- DOI
- https://doi.org/10.1134/s1070428025604431
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Russian Science Foundation
- Ministry of Science and Higher Education of the Russian Federation
- Russian Academy of Sciences