Development of a Flowsheet for Separating Boron Isotopes Using Liquid Extraction

The extraction system consisting of n-trioctylamine in o-xylene and an aqueous solution of boric and tartaric acids was chosen for separating boron isotopes by chemical exchange in a liquid–liquid system. The choice was based on the experimental data of the Khlopin Radium Institute and published data. An average separation factor of 1.02 was achieved. It was independent of the 10B content in the initial solution, which ranged from 20 to 96.6%. A principle for organizing a flowsheet of boric acid enrichment in 10B using liquid–liquid extraction with the return of a portion of the enriched product (reflux) was suggested.

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Publication Details

Journal
Radiochemistry
Published
2025-12-01
DOI
https://doi.org/10.1134/s1066362225060153
Primary Topic
Chemical Synthesis and Characterization
Type
article
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article

Development of a Flowsheet for Separating Boron Isotopes Using Liquid Extraction

Ya. O. Pleshakov, Yu. A. Naumova, A. S. Vissarionova, A. V. Dub et al.
Radiochemistry
Chemical Synthesis and Characterization
article

Development of a Flowsheet for Separating Boron Isotopes Using Liquid Extraction

Ya. O. Pleshakov, Yu. A. Naumova, A. S. Vissarionova, A. V. Dub, L. I. Tkachenko, E. V. Kenf, S. A. Krotov, E. A. Puzikov
article en

Abstract

The extraction system consisting of n-trioctylamine in o-xylene and an aqueous solution of boric and tartaric acids was chosen for separating boron isotopes by chemical exchange in a liquid–liquid system. The choice was based on the experimental data of the Khlopin Radium Institute and published data. An average separation factor of 1.02 was achieved. It was independent of the 10B content in the initial solution, which ranged from 20 to 96.6%. A principle for organizing a flowsheet of boric acid enrichment in 10B using liquid–liquid extraction with the return of a portion of the enriched product (reflux) was suggested.

RadiochemistryVol. 67(6)
V. G. Khlopin Radium Institute (RU), Institute of Professional Innovations (RU)
Clean water and sanitation
Openalex Percentile: Top 30%
Chemical Synthesis and Characterization
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