Dynamic processes of the first NHC-substituted rhenium heptahydrides [ReH <sub>7</sub> (NHC) <sub>2</sub> ]

Possible geometries and fluxional mechanisms of three [ReH $_{7}$ (NHC) $_{2}$ ] complexes (NHC = IMes (1), IMesCl $_{2}$ (2), and BIMes (3)) are presented. A new process named “η $_{2}$ -quadratic twist” has been identified. The complexes presented can perform C–H activation.

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Publication Details

Journal
Universität Zürich, ZORA
Published
2025-09-09
DOI
https://doi.org/10.5167/uzh-291046
Primary Topic
N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
Type
article
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article

Dynamic processes of the first NHC-substituted rhenium heptahydrides [ReH 7 (NHC) 2 ]

A. Pierini, M. Pierini, G. Grieco
Universität Zürich, ZORA
N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
article

Dynamic processes of the first NHC-substituted rhenium heptahydrides [ReH 7 (NHC) 2 ]

A. Pierini, M. Pierini, G. Grieco
article en

Abstract

Possible geometries and fluxional mechanisms of three [ReH $_{7}$ (NHC) $_{2}$ ] complexes (NHC = IMes (1), IMesCl $_{2}$ (2), and BIMes (3)) are presented. A new process named “η $_{2}$ -quadratic twist” has been identified. The complexes presented can perform C–H activation.

Universität Zürich, ZORA
Openalex Percentile: Top 31%
N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
DOIOpen Access PDFOpenAlex
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Dynamic processes of the first NHC-substituted rhenium heptahydrides [ReH <sub>7</sub> (NHC) <sub>2</sub> ] — A. Pierini, M. Pierini, et al. · Universität Zürich, ZORA (2025) | TGRS Research Map | TGRS