A Mild Protocol for Highly Congested and Functionalized C(sp <sup>3</sup> )–N Bonds Construction

A variety of sterically hindered and functionalized amines were easily constructed by transition-metal-free alkylation under mild conditions. A reactive conjugated anion intermediate was possibly involved.

Authors

Publication Details

Journal
The Journal of Organic Chemistry
Published
2026-02-05
DOI
https://doi.org/10.1021/acs.joc.5c02608
Primary Topic
Catalytic Cross-Coupling Reactions
Type
article
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article

A Mild Protocol for Highly Congested and Functionalized C(sp 3 )–N Bonds Construction

Chengming Wang, Lili Wu, Yifei Jiang
The Journal of Organic Chemistry
Catalytic Cross-Coupling Reactions
article

A Mild Protocol for Highly Congested and Functionalized C(sp 3 )–N Bonds Construction

Chengming Wang, Lili Wu, Yifei Jiang
article en

Abstract

A variety of sterically hindered and functionalized amines were easily constructed by transition-metal-free alkylation under mild conditions. A reactive conjugated anion intermediate was possibly involved.

The Journal of Organic ChemistryVol. 91(7)
Openalex Percentile: Top 63%
Catalytic Cross-Coupling Reactions
DOISourceOpenAlex
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A Mild Protocol for Highly Congested and Functionalized C(sp <sup>3</sup> )–N Bonds Construction — Chengming Wang, Lili Wu, et al. · The Journal of Organic Chemistry (2026) | TGRS Research Map | TGRS