Fertilization Effects of Recycled Phosphorus with CaAl-LDH Under Controlled Conditions

To mitigate the exhausting of phosphate rock (PR) reserves and the widespread water eutrophication due partially to excessive phosphorus (P), efficient adsorbents are valuable. Calcium (Ca) and aluminum (Al) containing layered double hydroxides (CaAl-LDHs) showed high P adsorption capacity and potential as slow-release P fertilizers, which merits further investigation. Two P proportions (5% and 10%) of P-adsorbed CaAl-LDHs (P-LDHs) were prepared, and its effects on various soil P contents and oilseed rape (Brassica napus L.) growth were evaluated. The main components of 5%P-LDH were P-intercalated CaAl-LDH and brushite, while 10%P-LDH mainly consisted of brushite. The proportions of P were extracted from 10%P-LDH and increased in the order of 4.9% (deionized water) < 48.9% (Olsen method) < 63.5% (Bray method) < 67.4% (citric acid), which suggested that 10%P-LDH could be citrate-soluble P fertilizer. 10%P-LDH showed similar effects on soil available P with single superphosphate (SSP). Both 5%- and 10%P-LDHs showed comparable improvement with SSP on aboveground dry weight of oilseed in the red soil, while being inapparent in the Fluvo-aquic soil. The CaAl-LDH appeared capable of providing Ca for rape growth in the low initial P concentration red soil, which showed the highest dry weight when combined with SSP. The recycled P-LDHs, especially 10%P-LDH, could supply P in a comparable manner with SSP for oilseed rape P uptake. Based on trials conducted under controlled conditions, our study suggested a promising production route of commercial P fertilizer alternatives via water P removal by CaAl-LDH. Further validations with realistic wastewater P removal by CaAl-LDH and via field scale growth trials are still needed before wide application of the alternative P fertilizer production procedure reported in the present study.