A Study on the Influence of Nitrogen Content on the Structural Performance and Stress Corrosion Resistance of 700 MPa Ultra-High-Strength Steel Bars

This study investigates the influence of vanadium–nitrogen (V-N) microalloying design on the microstructure and mechanical properties of 700 MPa grade ultra-high-strength steel bars. Through the control of the V/N ratio and cooling rate, a yield strength exceeding 700 MPa was achieved in a steel with a pearlite–ferrite matrix. Microstructural characterization via optical microscopy (OM) and scanning electron microscopy (SEM) revealed that a V/N ratio of approximately 1:10 combined with a rolling cooling rate of 1–3 °C/s resulted in the steel bar exhibiting a yield strength of 774.21 MPa and a tensile strength of 971.13 MPa. The primary microstructure of the steel consisted of ferrite and pearlite. The steel featured fine grains and favorable crystallographic orientations, which contributed to its high yield strength and good ductility. Transmission electron microscopy (TEM) analysis indicated that under hot-rolling conditions, vanadium precipitated predominantly as nano-scale V(C,N) particles. These precipitates were distributed in both the pearlite and ferrite phases, thereby enhancing the tensile and yield strength. Furthermore, the steel with an optimal nitrogen content (0.0166 wt.%) and the finest grain structure (average grain size ≈ 2.618 μm) showed the lowest stress corrosion cracking (SCC) susceptibility, characterized by an elongation loss rate (Iδ) of 12.51%, demonstrating excellent SCC resistance.