2-Cyano- <i>N</i> ′-[(1 <i>E</i> )-1-(3,4-dimethoxyphenyl)ethylidene]acetohydrazide

The non-H part of the mol-ecule of the title compound, C<sub>13</sub>H<sub>15</sub>N<sub>3</sub>O<sub>3</sub>, is nearly planar, with the 2-cyano-<i>N</i>'-[(1E)-ethyl-idene]acetohydrazide moiety and the dimeth-oxy phenol ring forming a dihedral angle of 2.5 (1)°. Inter-molecular N-H⋯O, C-H⋯O and C-H⋯π inter-actions are mainly responsible for the cohesion within the crystal structure. The inter-molecular inter-actions were qu-anti-fied and analysed using Hirshfeld surface analysis, revealing that H⋯H inter-actions contribute most to the crystal packing (36.9%). The volume of the crystal voids was calculated to be 167.8 Å<sup>3</sup> (13% of the unit-cell volume).

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IUCrData
Published
2026-01-28
DOI
https://doi.org/10.1107/s2414314626000891
Primary Topic
Crystal structures of chemical compounds
Type
article
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article

2-Cyano- N ′-[(1 E )-1-(3,4-dimethoxyphenyl)ethylidene]acetohydrazide

M. Manvizhi, S. Senthilkumar, Sivashanmugam Selvanayagam
IUCrData
Crystal structures of chemical compounds
article

2-Cyano- N ′-[(1 E )-1-(3,4-dimethoxyphenyl)ethylidene]acetohydrazide

M. Manvizhi, S. Senthilkumar, Sivashanmugam Selvanayagam
article en

Abstract

The non-H part of the mol-ecule of the title compound, C<sub>13</sub>H<sub>15</sub>N<sub>3</sub>O<sub>3</sub>, is nearly planar, with the 2-cyano-<i>N</i>'-[(1E)-ethyl-idene]acetohydrazide moiety and the dimeth-oxy phenol ring forming a dihedral angle of 2.5 (1)°. Inter-molecular N-H⋯O, C-H⋯O and C-H⋯π inter-actions are mainly responsible for the cohesion within the crystal structure. The inter-molecular inter-actions were qu-anti-fied and analysed using Hirshfeld surface analysis, revealing that H⋯H inter-actions contribute most to the crystal packing (36.9%). The volume of the crystal voids was calculated to be 167.8 Å<sup>3</sup> (13% of the unit-cell volume).

IUCrDataVol. 11(2)
Annamalai University (IN)
Openalex Percentile: Top 67%
Crystal structures of chemical compounds
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