Valorization of Lavender Agro-Waste into Functional Carbon Materials via Carbonization and Zn2+ Modification

This paper proposes a valorization approach for solid lavender residue, a by-product of the essential oil industry. The biomass residue was carbonized at atmospheric pressure and two temperatures (450 °C and 650 °C), followed by solvothermal modification with zinc ions (Zn²⁺, 3 and 5 mmol). The effects of temperature and Zn²⁺ incorporation on the elemental composition and morphology of the resulting biochar were examined using X-ray Fluorescence (XRF), Fourier Transform Infrared (FTIR) spectroscopy, and Scanning Electron Microscopy/Energy-Dispersive X-ray Spectroscopy (SEM/EDS) analyses. The applied Zn²⁺ modification was effective at both concentrations for the biochar obtained at both carbonization temperatures. However, a more uniform metal ion distribution was observed at 3 mmol, while at 5 mmol, a partial particle agglomeration occurred. Progressive degradation of the O-H, C=O, and C-O groups with increasing temperature and the presence of Zn-O-related interactions was observed. The results demonstrated consistent and reproducible trends, suggesting that controlled carbonization combined with Zn²⁺ incorporation can convert lavender residues into modified carbonaceous materials.