On the cocycle structure of the Boltzmann distribution

Abstract Based on a cocycle structure, we identify a new derivation of the Boltzmann distribution for finite energy-level systems from the maximal entropy principle (MEP). Our approach does not rely on the method of the Lagrange multiplier, and it provides a more transparent way to understand the dependence on the energy levels of the temperature T = 1/ β for the equilibrium distribution. Finally, we make two curious observations associated with our derivations.

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Publication Details

Journal
Transport Phenomena
Published
2026-02-04
DOI
https://doi.org/10.1515/tp-2026-0016
Primary Topic
Statistical Mechanics and Entropy
Type
article
Field-Weighted Citation Impact
0.00
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article

On the cocycle structure of the Boltzmann distribution

Chan-Yi Chang, Chuan-Tsung Chan, Zhong-Tang Wu
Transport Phenomena
Statistical Mechanics and Entropy
article

On the cocycle structure of the Boltzmann distribution

Chan-Yi Chang, Chuan-Tsung Chan, Zhong-Tang Wu
article en

Abstract

Abstract Based on a cocycle structure, we identify a new derivation of the Boltzmann distribution for finite energy-level systems from the maximal entropy principle (MEP). Our approach does not rely on the method of the Lagrange multiplier, and it provides a more transparent way to understand the dependence on the energy levels of the temperature T = 1/ β for the equilibrium distribution. Finally, we make two curious observations associated with our derivations.

Transport Phenomena
Tunghai University (TW)
Affordable and clean energy
Openalex Percentile: Top 67%
Statistical Mechanics and Entropy
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