Síntesis de surfactantes basados en ésteres/éteres de alquil glicerilo y evaluación como inhibidores de ceras

This study evaluated glycerol esters (GEC12, GEC14) and ethers (GEtC14, GEtC18) as alternative paraffin inhibitors compared with a commercial product (PI-CX). Rheological tests were performed on two crude oils (A and C). A cold finger assay was performed to measure wax deposition in a model system. PI-CX showed the best performance overall, but the synthesized molecules were also effective for oil A, reducing gelation temperature, viscosity, and yield stress. GEC12 showed slightly superior performance among the synthesized inhibitors. In the model system these inhibitors had the same performance. Although PI-CX proved to be more efficient, the new compounds are low cost, biodegradable, and effective under severe conditions (5 °C). Oil C, which did not gel down to –5 °C, showed no improvement with inhibitors, indicating that not all oils require treatment. The results support the potential of these glycerol-based compounds as sustainable alternatives for paraffin inhibition in specific crude oils.

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Publication Details

Journal
Magazine Portal Bibliotech Digital (Universidad Nacional de Colombia)
Published
2025-11-05
Primary Topic
Petroleum Processing and Analysis
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article
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article

Síntesis de surfactantes basados en ésteres/éteres de alquil glicerilo y evaluación como inhibidores de ceras

Elizabeth R. Lachter, Denise Gentili Nunes, Giovani Cavalcanti Nunes, ELIZABETE F LUCAS et al.
Magazine Portal Bibliotech Digital (Universidad Nacional de Colombia)
Petroleum Processing and Analysis
article

Síntesis de surfactantes basados en ésteres/éteres de alquil glicerilo y evaluación como inhibidores de ceras

Elizabeth R. Lachter, Denise Gentili Nunes, Giovani Cavalcanti Nunes, ELIZABETE F LUCAS, Agatha Oliveira Santos, Rita de Cássia Pessanha Nunes
article en

Abstract

This study evaluated glycerol esters (GEC12, GEC14) and ethers (GEtC14, GEtC18) as alternative paraffin inhibitors compared with a commercial product (PI-CX). Rheological tests were performed on two crude oils (A and C). A cold finger assay was performed to measure wax deposition in a model system. PI-CX showed the best performance overall, but the synthesized molecules were also effective for oil A, reducing gelation temperature, viscosity, and yield stress. GEC12 showed slightly superior performance among the synthesized inhibitors. In the model system these inhibitors had the same performance. Although PI-CX proved to be more efficient, the new compounds are low cost, biodegradable, and effective under severe conditions (5 °C). Oil C, which did not gel down to –5 °C, showed no improvement with inhibitors, indicating that not all oils require treatment. The results support the potential of these glycerol-based compounds as sustainable alternatives for paraffin inhibition in specific crude oils.

Magazine Portal Bibliotech Digital (Universidad Nacional de Colombia)
Responsible consumption and production
Openalex Percentile: Top 39%
Petroleum Processing and Analysis
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