Evaluation of the Relationship Between Fracture Toughness and Hydrogen-Induced Damage in X70 Line Pipe Steel for Low-Temperature Service

In this study, X70 line pipe steels were subjected to different hot rolling treatments under three conditions with varying roughing (R) and finishing (F) reductions while maintaining the same total reduction to investigate the effect on drop weight tear test (DWTT) toughness and hydrogen-induced damage as assessed through electrochemical charging. Scanning Electron Microscope (SEM) images were used to analyze microstructure phases and their volume fractions, while Electron Backscatter Diffraction (EBSD) provided quantitative microscopy, and X-ray analysis examined crystallographic texture. Although all steels exhibited similar microstructure phases, the effective grain size and morphology varied slightly across the thickness. As these variations were minor, the focus shifted to other microstructural features such as textural characteristics. Overall, the steel with the medium R/F reduction demonstrated improved DWTT performance and greater hydrogen cracking and blistering resistance. This was attributed to stronger Transformed Brass (TBr) and Transformed Copper (TC) components, weaker Rotated-Cube (RC) texture, and lower Kernel Average Misorientation (KAM) values. Across the three steels in this work, this study demonstrates that increased fraction of blocky austenite/martensite as secondary phases, high geometrically necessary dislocation (GND) density, and RC texture negatively affect both DWTT and hydrogen damage resistance, whereas gamma (γ)-fiber and {332}<113> textures have positive effects. Improving these metallurgical factors can therefore boost toughness and reduce hydrogen-induced damage in line-pipe steels.

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Publication Details

Journal
Materials
Published
2026-01-30
DOI
https://doi.org/10.3390/ma19030552
Primary Topic
Hydrogen embrittlement and corrosion behaviors in metals
Type
article
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article

Evaluation of the Relationship Between Fracture Toughness and Hydrogen-Induced Damage in X70 Line Pipe Steel for Low-Temperature Service

Sandeep Yadav, Enyinnaya Ohaeri, Jerzy A. Szpunar, Reza Khatib Zadeh Davani et al.
Materials
Hydrogen embrittlement and corrosion behaviors in metals
article

Evaluation of the Relationship Between Fracture Toughness and Hydrogen-Induced Damage in X70 Line Pipe Steel for Low-Temperature Service

Sandeep Yadav, Enyinnaya Ohaeri, Jerzy A. Szpunar, Reza Khatib Zadeh Davani, Ehsan Entezari, Michael J. Gaudet, Muhammad Rashid
article en

Abstract

In this study, X70 line pipe steels were subjected to different hot rolling treatments under three conditions with varying roughing (R) and finishing (F) reductions while maintaining the same total reduction to investigate the effect on drop weight tear test (DWTT) toughness and hydrogen-induced damage as assessed through electrochemical charging. Scanning Electron Microscope (SEM) images were used to analyze microstructure phases and their volume fractions, while Electron Backscatter Diffraction (EBSD) provided quantitative microscopy, and X-ray analysis examined crystallographic texture. Although all steels exhibited similar microstructure phases, the effective grain size and morphology varied slightly across the thickness. As these variations were minor, the focus shifted to other microstructural features such as textural characteristics. Overall, the steel with the medium R/F reduction demonstrated improved DWTT performance and greater hydrogen cracking and blistering resistance. This was attributed to stronger Transformed Brass (TBr) and Transformed Copper (TC) components, weaker Rotated-Cube (RC) texture, and lower Kernel Average Misorientation (KAM) values. Across the three steels in this work, this study demonstrates that increased fraction of blocky austenite/martensite as secondary phases, high geometrically necessary dislocation (GND) density, and RC texture negatively affect both DWTT and hydrogen damage resistance, whereas gamma (γ)-fiber and {332}<113> textures have positive effects. Improving these metallurgical factors can therefore boost toughness and reduce hydrogen-induced damage in line-pipe steels.

MaterialsVol. 19(3)
University of Regina (CA), University of Saskatchewan (CA)
Openalex Percentile: Top 75%
Hydrogen embrittlement and corrosion behaviors in metals
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