Photocatalytic Flow Synthesis of Sulfonates via Insertion Reactions of α‐Diazo Esters to Sulfonic Acids
ABSTRACT The insertion reactions of α‐diazo esters to sulfonic acids have been efficiently run in flow with visible light irradiation, leading to the practical synthesis of aryl and alkyl sulfonates under mild room temperature without using any catalyst. Besides the sustainable reaction conditions, the current method displays attractiveness for the broad substrate tolerance and practical scale‐up synthesis.
Authors
- Jie‐Ping Wan (ORCID: https://orcid.org/0000-0002-9367-8384)
- Fenghuai Wang
- Haijian Zhong
- Jiahao Tao
- Xiaoyan Song
- Liang Liu
- Mingzhe Hong
- Pu Liao
- Kai Cheng
- Wangqiang Wei
Institutions
- Nanjing Forestry University (CN)
- Shaoxing University (CN)
- Zhejiang Institute of Special Equipment Inspection (CN)
- Institute of New Materials (CN)
- Zhejiang Medicine (China) (CN)
- Jiangxi Normal University (CN)
Publication Details
- Journal
- ChemistrySelect
- Published
- 2026-01-30
- DOI
- https://doi.org/10.1002/slct.202600027
- Primary Topic
- Cyclopropane Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Zhejiang Province