AI-Assisted Physics-Informed Predictions of Degradation Behavior of Polymeric Anion Exchange Membranes

The global transition to hydrogen-based energy infrastructures faces significant hurdles. Chief among these are the high costs and sustainability issues associated with acid-based proton exchange membrane fuel cells. Anion exchange membrane (AEM) fuel cells offer promising cost-effective alternatives, yet their widespread adoption is limited by rapid degradation in alkaline environments. Here, we develop a framework that integrates mechanistic insights with machine learning, enabling the identification of generalized degradation behavior across diverse polymeric AEM chemistries and operating conditions. Our model successfully predicts long-term hydroxide conductivity degradation (up to 10,000 h) from minimal early time experimental data. This capability significantly reduces experimental burdens and may expedite the design of high-performance, durable AEM materials.

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Publication Details

Journal
The Journal of Physical Chemistry B
Published
2026-01-27
DOI
https://doi.org/10.1021/acs.jpcb.5c07063
Primary Topic
Fuel Cells and Related Materials
Type
article
Field-Weighted Citation Impact
0.00
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article

AI-Assisted Physics-Informed Predictions of Degradation Behavior of Polymeric Anion Exchange Membranes

Janani Sampath, Mohammed Al Otmi, William Schertzer, Rampi Ramprasad et al.
The Journal of Physical Chemistry B
Fuel Cells and Related Materials
article

AI-Assisted Physics-Informed Predictions of Degradation Behavior of Polymeric Anion Exchange Membranes

Janani Sampath, Mohammed Al Otmi, William Schertzer, Rampi Ramprasad, Ryan P. Lively
article en

Abstract

The global transition to hydrogen-based energy infrastructures faces significant hurdles. Chief among these are the high costs and sustainability issues associated with acid-based proton exchange membrane fuel cells. Anion exchange membrane (AEM) fuel cells offer promising cost-effective alternatives, yet their widespread adoption is limited by rapid degradation in alkaline environments. Here, we develop a framework that integrates mechanistic insights with machine learning, enabling the identification of generalized degradation behavior across diverse polymeric AEM chemistries and operating conditions. Our model successfully predicts long-term hydroxide conductivity degradation (up to 10,000 h) from minimal early time experimental data. This capability significantly reduces experimental burdens and may expedite the design of high-performance, durable AEM materials.

The Journal of Physical Chemistry BVol. 130(5)
Georgia Institute of Technology (US), University of Florida (US)
Industry, innovation and infrastructure
Openalex Percentile: Top 76%
Fuel Cells and Related Materials
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