Dichlorine-Containing Chlorothallate(III) (Me <sub>4</sub> N) <sub>3</sub> {[Tl <sub>2</sub> Cl <sub>9</sub> ](Cl <sub>2</sub> )}: Crystal Structure and Thermal Stability
The first example of a supramolecular complex of high-valent thallium(III)-containing "trapped" dichlorine, (Me<sub>4</sub>N)<sub>3</sub>{[Tl<sub>2</sub>Cl<sub>9</sub>](Cl<sub>2</sub>)} (<b>1</b>), has been prepared. <b>1</b> was characterized by X-ray single-crystal diffractometry, indicating the presence of the "trapped" dichlorine unit with prominent Cl···Cl noncovalent interactions. The complex demonstrates a relatively high thermal stability (up to 140 °C). Features of the Cl···Cl halogen contacts were examined by Raman spectroscopy.
Authors
- Ekaterina A. Radiush
- Andrey N. Usoltsev
- Nikita A. Korobeynikov
- Maxim N. Sokolov
- Sergey A. Adonin
- Nikolay A. Semenov
Institutions
- Novosibirsk Institute of Organic Chemistry (RU)
- A.E. Favorsky Irkutsk Institute of Chemistry (RU)
- Siberian Branch of the Russian Academy of Sciences (RU)
- Nikolaev Institute of Inorganic Chemistry (RU)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2026-01-27
- DOI
- https://doi.org/10.1021/acs.inorgchem.5c05013
- Primary Topic
- Synthesis and characterization of novel inorganic/organometallic compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00