Kinetics of Changes in Optical Properties upon Electron Irradiation of CaSiO3 Powder Modified with CeO2 Nanoparticles

We studied the kinetics of changes in the diffuse reflectance spectra and the integral absorption coefficient of solar radiation of the original CaSiO3 powder with µ-sized grains and modified with CeO2 nanoparticles at their optimal concentration of 3 wt % under electron irradiation (energy E = 30 keV, fluence Φ = (1–7) × 1016 cm–2) and the possibility of recording these properties in a vacuum at the irradiation site (in situ). Modification was found to lead to an increase in radiation resistance from 2.39 to 2.89 times depending on the electron fluence. The modification efficiency increases with increasing electron fluence during irradiation. The obtained results can be used to develop new radiation-resistant thermal control coatings of the “optical solar reflectors” class for spacecraft.

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Publication Details

Journal
Journal of Surface Investigation X-ray Synchrotron and Neutron Techniques
Published
2025-10-01
DOI
https://doi.org/10.1134/s1027451025701587
Primary Topic
Silicone and Siloxane Chemistry
Type
article
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article

Kinetics of Changes in Optical Properties upon Electron Irradiation of CaSiO3 Powder Modified with CeO2 Nanoparticles

S. A. Yuryev, D. S. Fedosov, V. A. Goronchko, A. N. Lapin et al.
Journal of Surface Investigation X-ray Synchrotron and Neutron Techniques
Silicone and Siloxane Chemistry
article

Kinetics of Changes in Optical Properties upon Electron Irradiation of CaSiO3 Powder Modified with CeO2 Nanoparticles

S. A. Yuryev, D. S. Fedosov, V. A. Goronchko, A. N. Lapin, M. M. Mikhailov
article en

Abstract

We studied the kinetics of changes in the diffuse reflectance spectra and the integral absorption coefficient of solar radiation of the original CaSiO3 powder with µ-sized grains and modified with CeO2 nanoparticles at their optimal concentration of 3 wt % under electron irradiation (energy E = 30 keV, fluence Φ = (1–7) × 1016 cm–2) and the possibility of recording these properties in a vacuum at the irradiation site (in situ). Modification was found to lead to an increase in radiation resistance from 2.39 to 2.89 times depending on the electron fluence. The modification efficiency increases with increasing electron fluence during irradiation. The obtained results can be used to develop new radiation-resistant thermal control coatings of the “optical solar reflectors” class for spacecraft.

Journal of Surface Investigation X-ray Synchrotron and Neutron TechniquesVol. 19(5)
Tomsk State University of Control Systems and Radio-Electronics (RU)
Affordable and clean energy
Openalex Percentile: Top 45%
Silicone and Siloxane Chemistry
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