Surface Free Energy Analysis Using the Washburn Capillary Rise Method to Improve the Accuracy of Measuring Carbon Fiber Interfacial Properties

The wettability of a carbon fiber surface is an important factor that determines the strength of its bonding with matrices, and hence, an optimized criterion is required to accurately measure the wettability. In this study, the Washburn capillary rise method was used to select the capillary constant with the minimal deviation among various carbon fiber lengths, and it was applied to determine the contact angle and surface free energy of each carbon fiber length according to the wetting liquid. The smallest deviation in the contact angle was observed for a carbon fiber length of 2 inches, and this observation was attributed to the pores in the fibers and the orientation of the carbon fibers packed inside the column. By reducing the number of pores and achieving favorable packing, the surface free energy of carbon fibers can be measured with a high degree of accuracy, contributing to an improved understanding of fiber–matrix interactions.