Effects of Milling-Medium Physicochemical Properties on Particle-Size Reduction and Surface Properties of Illite During Wet Ball Milling

Illite, a clay mineral, is used in diverse fields such as agriculture, cosmetics, and the food-related industry due to its many advantages, including biocompatibility, UV protection, antibacterial activity, high adsorption capacity for hazardous substances, and cost-effectiveness. However, its relatively large size, broad size distribution, and irregular morphology limit its broader applications. This study investigated the control of particle size and distribution during wet ball milling (WBM) using five media—acetone, ethanol, water, aqueous NaCl solution, and aqueous phosphoric acid solution—over milling times of 2–10 h. Prolonged milling progressively reduced particle size and narrowed the size distribution. Acetone and ethanol exhibited notably superior size-reduction performance compared with the aqueous systems, among which phosphoric acid solution showed the least effectiveness, likely attributed to variations in their physicochemical properties, including viscosity (η) and surface tension (σ), and in their interfacial interactions with illite. Optimal milling in acetone for 10 h resulted in the smallest particles (~700 nm), the narrowest distribution, the largest specific surface area, and the highest moisture retention. Overall, these findings demonstrate that the physicochemical properties of the milling medium, which govern WBM efficiency through fluid dynamics and particle–medium interactions, thereby determine the size and distribution of milled particles.