Oxygen Isotope Fingerprints of Electron-Phonon Coupling in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>SrVO</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>3</mml:mn> </mml:mrow> </mml:m
Transition metals exemplify correlated electronic systems, where electron-electron (e-e) scattering often results in a quadratic temperature dependence of the electrical resistivity, ρ(T)∝T^{2}. In SrVO_{3} (SVO), a material with a V-3d^{1} electronic configuration that ensures metallicity through narrow 3d-t_{2g} bands, a ρ(T)∝T^{2} dependence has been reported. While traditionally attributed to e-e scattering, recent studies suggest that electron-phonon (e-ph) interactions may play a significant role. To unravel the influence of phonon interactions on carrier transport in SVO, we present a comparative study of the transport and optical properties of SVO films with partial substitution of ^{16}O ions by their heavier isotope, ^{18}O. Our findings reveal that ^{18}O substitution induces a change in the slope of dρ(T)/dT at nominal fixed carrier density, highlighting the dominant contribution of e-ph coupling over e-e scattering in determining ρ(T). Furthermore, it is found that the ^{18}O substitution softens the phonon lattice and promotes a reduction in plasma frequency and an increase in the carrier effective mass. These results indicate that the e-ph coupling strength increases upon ^{18}O substitution. Our findings suggest that e-ph interactions may surpass e-e scattering in governing the resistivity of metallic ionic lattices.
Authors
- C. Schneider (ORCID: https://orcid.org/0000-0002-4292-8574)
- Mathieu Mirjolet (ORCID: https://orcid.org/0000-0002-8471-3184)
- J. Fontcuberta (ORCID: https://orcid.org/0000-0002-7955-2320)
- Thomas Lippert
- Anonymous
- Xiaochun Huang
- Salvador Pané
Institutions
- Paul Scherrer Institute (CH)
- ETH Zurich (CH)
- Institut de Ciència de Materials de Barcelona (ES)
- Institut Systèmes Intelligents et de Robotique (FR)
- Institute of Robotics
Publication Details
- Journal
- Physical Review Letters
- Published
- 2026-01-22
- DOI
- https://doi.org/10.1103/mtzb-b5ww
- Primary Topic
- Electronic and Structural Properties of Oxides
- Type
- article
- Field-Weighted Citation Impact
- 0.00