Oxygen Isotope Fingerprints of Electron-Phonon Coupling in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>SrVO</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>3</mml:mn> </mml:mrow> </mml:m

Transition metals exemplify correlated electronic systems, where electron-electron (e-e) scattering often results in a quadratic temperature dependence of the electrical resistivity, ρ(T)∝T^{2}. In SrVO_{3} (SVO), a material with a V-3d^{1} electronic configuration that ensures metallicity through narrow 3d-t_{2g} bands, a ρ(T)∝T^{2} dependence has been reported. While traditionally attributed to e-e scattering, recent studies suggest that electron-phonon (e-ph) interactions may play a significant role. To unravel the influence of phonon interactions on carrier transport in SVO, we present a comparative study of the transport and optical properties of SVO films with partial substitution of ^{16}O ions by their heavier isotope, ^{18}O. Our findings reveal that ^{18}O substitution induces a change in the slope of dρ(T)/dT at nominal fixed carrier density, highlighting the dominant contribution of e-ph coupling over e-e scattering in determining ρ(T). Furthermore, it is found that the ^{18}O substitution softens the phonon lattice and promotes a reduction in plasma frequency and an increase in the carrier effective mass. These results indicate that the e-ph coupling strength increases upon ^{18}O substitution. Our findings suggest that e-ph interactions may surpass e-e scattering in governing the resistivity of metallic ionic lattices.

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Journal
Physical Review Letters
Published
2026-01-22
DOI
https://doi.org/10.1103/mtzb-b5ww
Primary Topic
Electronic and Structural Properties of Oxides
Type
article
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Oxygen Isotope Fingerprints of Electron-Phonon Coupling in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>SrVO</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>3</mml:mn> </mml:mrow> </mml:m

C. Schneider, Mathieu Mirjolet, J. Fontcuberta, Thomas Lippert et al.
Physical Review Letters
Electronic and Structural Properties of Oxides
article

Oxygen Isotope Fingerprints of Electron-Phonon Coupling in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>SrVO</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>3</mml:mn> </mml:mrow> </mml:m

C. Schneider, Mathieu Mirjolet, J. Fontcuberta, Thomas Lippert, Anonymous, Xiaochun Huang, Salvador Pané
article en

Abstract

Transition metals exemplify correlated electronic systems, where electron-electron (e-e) scattering often results in a quadratic temperature dependence of the electrical resistivity, ρ(T)∝T^{2}. In SrVO_{3} (SVO), a material with a V-3d^{1} electronic configuration that ensures metallicity through narrow 3d-t_{2g} bands, a ρ(T)∝T^{2} dependence has been reported. While traditionally attributed to e-e scattering, recent studies suggest that electron-phonon (e-ph) interactions may play a significant role. To unravel the influence of phonon interactions on carrier transport in SVO, we present a comparative study of the transport and optical properties of SVO films with partial substitution of ^{16}O ions by their heavier isotope, ^{18}O. Our findings reveal that ^{18}O substitution induces a change in the slope of dρ(T)/dT at nominal fixed carrier density, highlighting the dominant contribution of e-ph coupling over e-e scattering in determining ρ(T). Furthermore, it is found that the ^{18}O substitution softens the phonon lattice and promotes a reduction in plasma frequency and an increase in the carrier effective mass. These results indicate that the e-ph coupling strength increases upon ^{18}O substitution. Our findings suggest that e-ph interactions may surpass e-e scattering in governing the resistivity of metallic ionic lattices.

Physical Review LettersVol. 136(7)
Paul Scherrer Institute (CH), ETH Zurich (CH), Institut de Ciència de Materials de Barcelona (ES), Institut Systèmes Intelligents et de Robotique (FR), Institute of Robotics
Openalex Percentile: Top 81%
Electronic and Structural Properties of Oxides
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