Algebraic Loop Liquid in the Pyrochlore <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>CsNiCrF</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>6</mml:mn> </mml:mrow> </mml:msub> </mml:mrow>

The β-pyrochlore CsNiCrF_{6} is a charge ice-each tetrahedron of the pyrochlore lattice is occupied by two Ni^{2+} and two Cr^{3+} according to an ice rule, resulting in fully packed same-species loops with power-law length distribution. Using inelastic neutron scattering and numerical simulations, we show that the spin dynamics can be well described by a model with three antiferromagnetic interaction strengths, one for Ni-Ni, Cr-Ni, and Cr-Cr interactions. Because the strengths of the two intraloop interactions are quite different, the fluctuations of each type of loop can be identified in the spectrum. CsNiCrF_{6} therefore forms an algebraic loop liquid in which power-law cation correlations control the spin dynamics. Our parameters predict a transition to spin nematic order with associated arrest of dynamics at T_{n}≈0.55 K, while we observe a freezing transition at T_{f}=2.3 K. Measurements of magnetization, ac, and nonlinear susceptibility show that this is not a canonical spin glass transition so we associate it with the development of slow dynamics due to interloop nematic correlations.

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Journal
Physical Review Letters
Published
2026-01-22
DOI
https://doi.org/10.1103/xvxt-whns
Primary Topic
Nuclear materials and radiation effects
Type
article
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article

Algebraic Loop Liquid in the Pyrochlore <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>CsNiCrF</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>6</mml:mn> </mml:mrow> </mml:msub> </mml:mrow>

Christian Balz, M. Medarde, Jacques Ollivier, A. dos Santos Rufino et al.
Physical Review Letters
Nuclear materials and radiation effects
article

Algebraic Loop Liquid in the Pyrochlore <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>CsNiCrF</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>6</mml:mn> </mml:mrow> </mml:msub> </mml:mrow>

Christian Balz, M. Medarde, Jacques Ollivier, A. dos Santos Rufino, P. M. Derlet, T. Fennell, Ø. S. Fjellvåg, N. Colonna, E. Lhotel, G. J. Nilsen, M. J. Harris, S. T. Bramwell
article en

Abstract

The β-pyrochlore CsNiCrF_{6} is a charge ice-each tetrahedron of the pyrochlore lattice is occupied by two Ni^{2+} and two Cr^{3+} according to an ice rule, resulting in fully packed same-species loops with power-law length distribution. Using inelastic neutron scattering and numerical simulations, we show that the spin dynamics can be well described by a model with three antiferromagnetic interaction strengths, one for Ni-Ni, Cr-Ni, and Cr-Cr interactions. Because the strengths of the two intraloop interactions are quite different, the fluctuations of each type of loop can be identified in the spectrum. CsNiCrF_{6} therefore forms an algebraic loop liquid in which power-law cation correlations control the spin dynamics. Our parameters predict a transition to spin nematic order with associated arrest of dynamics at T_{n}≈0.55 K, while we observe a freezing transition at T_{f}=2.3 K. Measurements of magnetization, ac, and nonlinear susceptibility show that this is not a canonical spin glass transition so we associate it with the development of slow dynamics due to interloop nematic correlations.

Physical Review LettersVol. 136(10)
Institute for Energy Technology (NO), University of Oxford (GB), Crystal Research (United States) (US), Institut Laue-Langevin (FR), Institut Néel (FR), ISIS Neutron and Muon Source, University College London (GB)
Openalex Percentile: Top 81%
Nuclear materials and radiation effects
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