Mobility-induced phase separation in a binary mixture of active Brownian particles

In this paper, we report a Brownian dynamics simulation of the mobility-induced phase separation that occurs in a two-dimensional binary mixture of active soft Brownian particles, whose interactions are modeled by non-additive Weeks-Chandler-Andersen potentials inspired by Lennard-Jones potentials used for glass-forming passive mixtures. The analysis of structural properties, such as the radial distribution functions and the hexatic order parameter, shows that the high-density coexisting state in the binary case is spatially disordered, unlike the solid-like state observed for the monocomponent system. The characterization of the mean-square displacement of the active particles shows that both the low- and high-density coexisting states have diffusive behavior for long times. Therefore, the high-density coexisting states are liquid-like in the binary cases. Moreover, diffusive behavior is also observed in the high-density solid-like state for the monocomponent system, which is driven by the presence of active topological defects.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2026-01-22
DOI
https://doi.org/10.1063/5.0304795
Primary Topic
Micro and Nano Robotics
Type
article
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article

Mobility-induced phase separation in a binary mixture of active Brownian particles

José Enríque, Álvaro Rodríguez-Rivas, Daniel Jiménez-Flores
The Journal of Chemical Physics
Micro and Nano Robotics
article

Mobility-induced phase separation in a binary mixture of active Brownian particles

José Enríque, Álvaro Rodríguez-Rivas, Daniel Jiménez-Flores
article en

Abstract

In this paper, we report a Brownian dynamics simulation of the mobility-induced phase separation that occurs in a two-dimensional binary mixture of active soft Brownian particles, whose interactions are modeled by non-additive Weeks-Chandler-Andersen potentials inspired by Lennard-Jones potentials used for glass-forming passive mixtures. The analysis of structural properties, such as the radial distribution functions and the hexatic order parameter, shows that the high-density coexisting state in the binary case is spatially disordered, unlike the solid-like state observed for the monocomponent system. The characterization of the mean-square displacement of the active particles shows that both the low- and high-density coexisting states have diffusive behavior for long times. Therefore, the high-density coexisting states are liquid-like in the binary cases. Moreover, diffusive behavior is also observed in the high-density solid-like state for the monocomponent system, which is driven by the presence of active topological defects.

The Journal of Chemical PhysicsVol. 164(4)
Universidad de Granada (ES), Universidad de Sevilla (ES)
Openalex Percentile: Top 77%
Micro and Nano Robotics
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Mobility-induced phase separation in a binary mixture of active Brownian particles — José Enríque, Álvaro Rodríguez-Rivas, et al. · The Journal of Chemical Physics (2026) | TGRS Research Map | TGRS