Integrated NiO2-catalyzed reforming of sesame stalk for hydrogen-enriched producer gas and dual-fuel CI engine performance evaluation
The present study develops a unified experimental framework integrating biomass gasification, NiO 2 -based catalytic reforming, and dual-fuel engine testing to produce and utilize hydrogen-enriched producer gas derived from Sesamum indicum (sesame) stalks. While prior studies have independently explored gasification, catalytic upgrading, or engine combustion, no previous work has experimentally coupled these domains within a single closed-loop system. In this research, a fixed-bed downdraft gasifier equipped with a NiO 2 -impregnated catalytic reformer was designed to generate hydrogen-rich producer gas at flowrates of 2 and 4 L/min, achieving an H 2 concentration of 39.5 vol% and a calorific value of 6.4 MJ/Nm 3 . The integration of NiO 2 catalysis enhanced hydrogen yield by 113 % and increased gas heating value by 25.5 % compared with the non-catalytic case. Engine performance evaluation under dual-fuel operation demonstrated that 2 L/min hydrogen-enriched gas with diesel achieved the highest brake thermal efficiency (29.8 %) and the lowest specific fuel consumption (0.249 kg/kWh). Emission analysis revealed reductions of 44 % in CO and 35 % in HC, with a minor 1.5 % increase in NO x due to higher adiabatic temperatures. Combustion diagnostics confirmed a 20.8 % rise in peak cylinder pressure (74.46 bar) and a 10.6 % reduction in ignition delay (10.1°CA). The study fills a critical research gap by demonstrating a NiO 2 -catalyzed biomass-to-engine hydrogen pathway, thereby establishing a scalable model for decentralized power generation and sustainable hydrogen utilization from agricultural residues. • NiO 2 -catalytic reformer boosted H 2 yield by 113 % and energy density by 25.5 %. • Hydrogen-enriched gas (39.5 vol%) produced from sesame stalk in a downdraft reactor. • Dual-fuel CI engine achieved 29.8 % BTE and 22 % lower specific fuel consumption. • CO and HC emissions reduced by 44 % and 35 % under catalytic reforming conditions. • Integrated gasification–reforming–engine loop enables decentralized hydrogen energy.
Authors
- Silambarasan Rajendran (ORCID: https://orcid.org/0000-0003-4017-5940)
- Mamdooh Alwetaishi (ORCID: https://orcid.org/0000-0001-5053-4324)
- Ali Keçebaş (ORCID: https://orcid.org/0000-0003-4809-2461)
- Elumalai Perumal Venkatesan
- Anbuchezian Ashokan
- Fayaz Hussain
- Sudagar Subramanian
- R. Thamizhvel
Institutions
- Universiti Putra Malaysia (MY)
- Taif University (SA)
- ASA College (US)
- Anna University, Chennai (IN)
- Aditya Birla (India) (IN)
- Chitkara University (IN)
- Muğla University (TR)
- Saveetha University (IN)
Publication Details
- Journal
- International Journal of Hydrogen Energy
- Published
- 2026-01-20
- DOI
- https://doi.org/10.1016/j.ijhydene.2025.153333
- Primary Topic
- Thermochemical Biomass Conversion Processes
- Type
- article
- Field-Weighted Citation Impact
- 0.00