Integrated NiO2-catalyzed reforming of sesame stalk for hydrogen-enriched producer gas and dual-fuel CI engine performance evaluation

The present study develops a unified experimental framework integrating biomass gasification, NiO 2 -based catalytic reforming, and dual-fuel engine testing to produce and utilize hydrogen-enriched producer gas derived from Sesamum indicum (sesame) stalks. While prior studies have independently explored gasification, catalytic upgrading, or engine combustion, no previous work has experimentally coupled these domains within a single closed-loop system. In this research, a fixed-bed downdraft gasifier equipped with a NiO 2 -impregnated catalytic reformer was designed to generate hydrogen-rich producer gas at flowrates of 2 and 4 L/min, achieving an H 2 concentration of 39.5 vol% and a calorific value of 6.4 MJ/Nm 3 . The integration of NiO 2 catalysis enhanced hydrogen yield by 113 % and increased gas heating value by 25.5 % compared with the non-catalytic case. Engine performance evaluation under dual-fuel operation demonstrated that 2 L/min hydrogen-enriched gas with diesel achieved the highest brake thermal efficiency (29.8 %) and the lowest specific fuel consumption (0.249 kg/kWh). Emission analysis revealed reductions of 44 % in CO and 35 % in HC, with a minor 1.5 % increase in NO x due to higher adiabatic temperatures. Combustion diagnostics confirmed a 20.8 % rise in peak cylinder pressure (74.46 bar) and a 10.6 % reduction in ignition delay (10.1°CA). The study fills a critical research gap by demonstrating a NiO 2 -catalyzed biomass-to-engine hydrogen pathway, thereby establishing a scalable model for decentralized power generation and sustainable hydrogen utilization from agricultural residues. • NiO 2 -catalytic reformer boosted H 2 yield by 113 % and energy density by 25.5 %. • Hydrogen-enriched gas (39.5 vol%) produced from sesame stalk in a downdraft reactor. • Dual-fuel CI engine achieved 29.8 % BTE and 22 % lower specific fuel consumption. • CO and HC emissions reduced by 44 % and 35 % under catalytic reforming conditions. • Integrated gasification–reforming–engine loop enables decentralized hydrogen energy.

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Publication Details

Journal
International Journal of Hydrogen Energy
Published
2026-01-20
DOI
https://doi.org/10.1016/j.ijhydene.2025.153333
Primary Topic
Thermochemical Biomass Conversion Processes
Type
article
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article

Integrated NiO2-catalyzed reforming of sesame stalk for hydrogen-enriched producer gas and dual-fuel CI engine performance evaluation

Silambarasan Rajendran, Mamdooh Alwetaishi, Ali Keçebaş, Elumalai Perumal Venkatesan et al.
International Journal of Hydrogen Energy
Thermochemical Biomass Conversion Processes
article

Integrated NiO2-catalyzed reforming of sesame stalk for hydrogen-enriched producer gas and dual-fuel CI engine performance evaluation

Silambarasan Rajendran, Mamdooh Alwetaishi, Ali Keçebaş, Elumalai Perumal Venkatesan, Anbuchezian Ashokan, Fayaz Hussain, Sudagar Subramanian, R. Thamizhvel
article en

Abstract

The present study develops a unified experimental framework integrating biomass gasification, NiO 2 -based catalytic reforming, and dual-fuel engine testing to produce and utilize hydrogen-enriched producer gas derived from Sesamum indicum (sesame) stalks. While prior studies have independently explored gasification, catalytic upgrading, or engine combustion, no previous work has experimentally coupled these domains within a single closed-loop system. In this research, a fixed-bed downdraft gasifier equipped with a NiO 2 -impregnated catalytic reformer was designed to generate hydrogen-rich producer gas at flowrates of 2 and 4 L/min, achieving an H 2 concentration of 39.5 vol% and a calorific value of 6.4 MJ/Nm 3 . The integration of NiO 2 catalysis enhanced hydrogen yield by 113 % and increased gas heating value by 25.5 % compared with the non-catalytic case. Engine performance evaluation under dual-fuel operation demonstrated that 2 L/min hydrogen-enriched gas with diesel achieved the highest brake thermal efficiency (29.8 %) and the lowest specific fuel consumption (0.249 kg/kWh). Emission analysis revealed reductions of 44 % in CO and 35 % in HC, with a minor 1.5 % increase in NO x due to higher adiabatic temperatures. Combustion diagnostics confirmed a 20.8 % rise in peak cylinder pressure (74.46 bar) and a 10.6 % reduction in ignition delay (10.1°CA). The study fills a critical research gap by demonstrating a NiO 2 -catalyzed biomass-to-engine hydrogen pathway, thereby establishing a scalable model for decentralized power generation and sustainable hydrogen utilization from agricultural residues. • NiO 2 -catalytic reformer boosted H 2 yield by 113 % and energy density by 25.5 %. • Hydrogen-enriched gas (39.5 vol%) produced from sesame stalk in a downdraft reactor. • Dual-fuel CI engine achieved 29.8 % BTE and 22 % lower specific fuel consumption. • CO and HC emissions reduced by 44 % and 35 % under catalytic reforming conditions. • Integrated gasification–reforming–engine loop enables decentralized hydrogen energy.

International Journal of Hydrogen EnergyVol. 209
Universiti Putra Malaysia (MY), Taif University (SA), ASA College (US), Anna University, Chennai (IN), Aditya Birla (India) (IN), Chitkara University (IN), Muğla University (TR), Saveetha University (IN)
Zero hunger
Openalex Percentile: Top 83%
Thermochemical Biomass Conversion Processes
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