Synthesis and structure of <i>catena</i> -poly[[[bis(pyridin-2-yl)amine]cadmium(II)]-di-μ <sub>2</sub> -azido]
In the title compound, [Cd(N<sub>3</sub>)<sub>2</sub>(C<sub>10</sub>H<sub>9</sub>N<sub>3</sub>)] <sub><i>n</i></sub> , the cadmium(II) ion displays a distorted CdN<sub>6</sub> octa-hedral geometry arising from one bidentate ligand and four azide ions and forms zigzag polymeric [100] chains <i>via</i> the bridging azide ions, both of which show μ<sub>1,1</sub> (end-on) coordination. Adjacent chains are linked into layers <i>via</i> N-H⋯N hydrogen bonds. Hirshfeld surface analysis was used to qu-antify the inter-molecular inter-actions.
Authors
- Joel T. Mague (ORCID: https://orcid.org/0000-0003-3488-1945)
- Mohammed Hadi Al-Douh
- Fatima Setifi
- Zouaoui Setifi
Institutions
- Tulane University (US)
- Hadhramout University (YE)
- University Ferhat Abbas of Setif (DZ)
- University of Skikda (DZ)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2026-01-13
- DOI
- https://doi.org/10.1107/s2056989026000289
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.00