Enthalpies of Formation of Hexaaluminates EuMg0.8Al11O18.8 and GdMg0.8Al11O18.8

Hexaaluminates EuMg0.8Al11O18.8 and GdMg0.8Al11O18.8 with a magnetoplumbite structure were prepared by the citrate sol-gel method and identified by X-ray diffraction analysis, scanning electron microscopy, and EDX-spectroscopy. The enthalpies of formation of EuMg0.8Al11O18.8 and GdMg0.8Al11O18.8 from oxides and elements at 298.15 K were determined from the enthalpies of solution in molten lead borate.

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Publication Details

Journal
Russian Journal of Physical Chemistry A
Published
2025-12-01
DOI
https://doi.org/10.1134/s0036024425702711
Primary Topic
Molten salt chemistry and electrochemical processes
Type
article
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article

Enthalpies of Formation of Hexaaluminates EuMg0.8Al11O18.8 and GdMg0.8Al11O18.8

M. A. Ryumin, P. G. Gagarin, A. V. Guskov, A. V. Khvan et al.
Russian Journal of Physical Chemistry A
Molten salt chemistry and electrochemical processes
article

Enthalpies of Formation of Hexaaluminates EuMg0.8Al11O18.8 and GdMg0.8Al11O18.8

M. A. Ryumin, P. G. Gagarin, A. V. Guskov, A. V. Khvan, I. A. Bazhenova, S. V. Kuzovchikov, V. N. Guskov, K. S. Gavrichev
article en

Abstract

Hexaaluminates EuMg0.8Al11O18.8 and GdMg0.8Al11O18.8 with a magnetoplumbite structure were prepared by the citrate sol-gel method and identified by X-ray diffraction analysis, scanning electron microscopy, and EDX-spectroscopy. The enthalpies of formation of EuMg0.8Al11O18.8 and GdMg0.8Al11O18.8 from oxides and elements at 298.15 K were determined from the enthalpies of solution in molten lead borate.

Russian Journal of Physical Chemistry AVol. 99(13)
Lomonosov Moscow State University (RU), NS Kurnakova Institute of General and Inorganic Chemistry (RU)
Openalex Percentile: Top 43%
Molten salt chemistry and electrochemical processes
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