Synthesis and structure of {methyl ( <i>Z</i> )-2-[4-(dimethylamino)benzylidene]hydrazine-1-carbodithioate-κ <sup>2</sup> <i>N</i> <sup>2</sup> , <i>S</i> }bis(triphenylphosphine-κ <i>P</i> )copper(I) nitrate carbon tetrachloride monosolvate
In the title compound, [Cu(C<sub>11</sub>H<sub>15</sub>N<sub>3</sub>S<sub>2</sub>){P(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>}<sub>2</sub>]NO<sub>3</sub>·CCl<sub>4</sub>, the carbon tetra-chloride solvent mol-ecule is presumed to have originated as an impurity in the chloro-form solvent used. The coordination environment around the copper(I) ion is a distorted CuNSP<sub>2</sub> tetra-hedron, with a τ<sub>4</sub> structural index of 0.844. In the extended structure, the cation and anion are linked by an N-H⋯O hydrogen bond. Along with electrostatic forces, C-H⋯N, C-H⋯S and C-H⋯O hydrogen bonds help to consolidate the crystal packing.
Authors
- Marappan Velusamy (ORCID: https://orcid.org/0000-0001-6488-8000)
- Loko Abraham
- Thangaraja Chinnathangavel
- Kolandaivelu Saminathan
- A. Arunkumar
- Banmankhraw Dkhar
- Venugopal Rajendiran
Institutions
- Central University of Tamil Nadu (IN)
- North Eastern Hill University (IN)
- Vitrina University (AL)
- Anna University, Chennai (IN)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2026-01-12
- DOI
- https://doi.org/10.1107/s2056989026000228
- Citations
- 1
- Primary Topic
- Metal complexes synthesis and properties
- Type
- article
- Field-Weighted Citation Impact
- 24.20