Higher-order Derivative Voltabsorptmetry of Tris(acetylacetonato)iron (III) Complex in Acetonitrile

A voltaborptmetric property of tris(acetylacetonato)iron (III) (Fe(acac)3) in acetonitrile in an optically transparent thin layer cell was investigated.The obtained electronic absorption spectra were analyzed using the higher-order derivative conversion (HODC) up to the eighth order.The Nernst equation can analyze the potential dependence of the sub-peak obtained by the HODC, and the HODC method is shown to be effective for studying the spectroelectrochemistry of metal complexes dissolved in non-aqueous systems.

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Publication Details

Journal
Electrochemistry
Published
2026-01-15
DOI
https://doi.org/10.5796/electrochemistry.25-00174
Primary Topic
Metal-Catalyzed Oxygenation Mechanisms
Type
article
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article

Higher-order Derivative Voltabsorptmetry of Tris(acetylacetonato)iron (III) Complex in Acetonitrile

Shinya KISHIOKA
Electrochemistry
Metal-Catalyzed Oxygenation Mechanisms
article

Higher-order Derivative Voltabsorptmetry of Tris(acetylacetonato)iron (III) Complex in Acetonitrile

Shinya KISHIOKA
article en

Abstract

A voltaborptmetric property of tris(acetylacetonato)iron (III) (Fe(acac)3) in acetonitrile in an optically transparent thin layer cell was investigated.The obtained electronic absorption spectra were analyzed using the higher-order derivative conversion (HODC) up to the eighth order.The Nernst equation can analyze the potential dependence of the sub-peak obtained by the HODC, and the HODC method is shown to be effective for studying the spectroelectrochemistry of metal complexes dissolved in non-aqueous systems.

ElectrochemistryVol. 94(2)
Gunma University (JP)
Openalex Percentile: Top 87%
Metal-Catalyzed Oxygenation Mechanisms
DOIOpen Access PDFOpenAlex
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Higher-order Derivative Voltabsorptmetry of Tris(acetylacetonato)iron (III) Complex in Acetonitrile — Shinya KISHIOKA · Electrochemistry (2026) | TGRS Research Map | TGRS