Synthesis of 5′-Chlorospiro(benzo[d][1,3]dioxole-2,4′-[1,2,6]thiadiazin)-3′-amine and 10-Chloro-1,4-dioxa-8-thia-7,9-diazaspiro[4.5]deca-6,9-dien-6-amine
Reactions of 3′,5′-dichlorospiro(benzo[d][1,3]dioxole-2,4′-[1,2,6]thiadiazine) or 6,10-dichloro-1,4-dioxa-8-thia-7,9-diazaspiro[4.5]deca-6,9-diene with ammonia in MeCN, at ca. 20 °C, gave 5′-chlorospiro(benzo[d][1,3]dioxole-2,4′-[1,2,6]thiadiazin)-3′-amine and 10-chloro-1,4-dioxa-8-thia-7,9-diazaspiro[4.5]deca-6,9-dien-6-amine, respectively, in near quantitative yields.
Authors
- Andreas S. Kalogirou (ORCID: https://orcid.org/0000-0002-5476-5805)
- Panayiotis A. Koutentis (ORCID: https://orcid.org/0000-0002-4652-7567)
Institutions
- European University Cyprus (CY)
- University of Cyprus (CY)
Publication Details
- Journal
- Molbank
- Published
- 2026-01-16
- DOI
- https://doi.org/10.3390/m2125
- Primary Topic
- Structural and Chemical Analysis of Organic and Inorganic Compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- University of Cyprus
- A.G. Leventis Foundation