Temperature dependence and physical interpretation of the self-continuum absorption of water vapor in the 1.6  <i>μ</i> m window

New measurements of the very weak water vapor self-continuum absorption are reported by cavity ring down spectroscopy (CRDS) in the 1.6 μm window. For 30 selected spectral points ranging between 5702 and 6855 cm-1, the temperature dependence of the self-continuum cross section is studied by monitoring the absorption during pressure ramps of pure water vapor at 285, 296, 308, 317, and 332 K. For each measurement point, the self-continuum cross section, CS(T), was retrieved from the purely quadratic pressure dependence of the measured absorption coefficient, after subtraction of the monomer lines contribution. The temperature dependence was studied with a highly stable temperature regulated CRDS cell, allowing for a significant gain compared to a first study [Mondelain et al., J. Geophys. Res. Atmos. 119, 5625-5639 (2014)]. Although some significant deviations are evidenced, an overall good agreement with the MT_CKD model of the self-continuum is noted. In the low energy range of the window, the predictions based on the far-wing line function obtained by Ma et al. [J. Chem. Phys. 128, 124313 (2008)] show an excellent agreement with the measurements. This is not the case in the high-energy range of the window where far-wing predictions underestimate both the cross sections and the temperature dependence. Semi-empirical simulations indicate that the missing absorption in that interval is due to the contribution of the quasi-bound water dimers. The comparison of the simulations with the MT_CKD model in the 0-10000 cm-1 range indicates that the hybrid interpretation of the origin of the continuum proposed in the 1.6 μm window applies to other transparency windows.

Authors

Institutions

Publication Details

Journal
The Journal of Chemical Physics
Published
2026-01-16
DOI
https://doi.org/10.1063/5.0312219
Primary Topic
Spectroscopy and Laser Applications
Type
article
Field-Weighted Citation Impact
0.00
Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Temperature dependence and physical interpretation of the self-continuum absorption of water vapor in the 1.6  μ m window

S. Béguier, M. Toureille, A. Campargue, D. Mondelain
The Journal of Chemical Physics
Spectroscopy and Laser Applications
article

Temperature dependence and physical interpretation of the self-continuum absorption of water vapor in the 1.6  μ m window

S. Béguier, M. Toureille, A. Campargue, D. Mondelain
article en

Abstract

New measurements of the very weak water vapor self-continuum absorption are reported by cavity ring down spectroscopy (CRDS) in the 1.6 μm window. For 30 selected spectral points ranging between 5702 and 6855 cm-1, the temperature dependence of the self-continuum cross section is studied by monitoring the absorption during pressure ramps of pure water vapor at 285, 296, 308, 317, and 332 K. For each measurement point, the self-continuum cross section, CS(T), was retrieved from the purely quadratic pressure dependence of the measured absorption coefficient, after subtraction of the monomer lines contribution. The temperature dependence was studied with a highly stable temperature regulated CRDS cell, allowing for a significant gain compared to a first study [Mondelain et al., J. Geophys. Res. Atmos. 119, 5625-5639 (2014)]. Although some significant deviations are evidenced, an overall good agreement with the MT_CKD model of the self-continuum is noted. In the low energy range of the window, the predictions based on the far-wing line function obtained by Ma et al. [J. Chem. Phys. 128, 124313 (2008)] show an excellent agreement with the measurements. This is not the case in the high-energy range of the window where far-wing predictions underestimate both the cross sections and the temperature dependence. Semi-empirical simulations indicate that the missing absorption in that interval is due to the contribution of the quasi-bound water dimers. The comparison of the simulations with the MT_CKD model in the 0-10000 cm-1 range indicates that the hybrid interpretation of the origin of the continuum proposed in the 1.6 μm window applies to other transparency windows.

The Journal of Chemical PhysicsVol. 164(3)
Centre National de la Recherche Scientifique (FR), Laboratoire Interdisciplinaire de Physique (FR), Université Grenoble Alpes (FR)
Clean water and sanitation
Openalex Percentile: Top 87%
Spectroscopy and Laser Applications
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.