The Influence of Microstructure on Decisions Regarding Repurposing Natural Gas Pipelines for Hydrogen Service

Empirical approaches alone have significant limitations for accurate estimation of the fracture toughness of welds in gas line pipes being considered for repurposing to hydrogen service. These problems arise because most samples machined from ex-service welds contain a range of microstructures. The different microstructural zones have different properties and even when compact tension samples with side grooves are utilized, it is unlikely that plane strain conditions are achieved during laboratory testing. Thus, the measured toughness may not be directly relevant to assessing in-service performance. The present research has been undertaken as part of an integrated series of projects seeking to define a robust protocol for assessing the damage tolerance of piping used for the transmission of hydrogen, especially when considering repurposing existing infrastructure. The key work described in this paper involved establishing heat treatments which produced microstructures relevant to the constituents found in ex-service welds of X46 type steel. Following comprehensive microstructural characterization, these heat treatments were applied to steel sections which allowed for the fabrication of standard compact tension specimens, which were subsequently tested in hydrogen to measure fracture toughness. The results obtained showed that the fracture behavior varied for different microstructures. To identify the influence that hydrogen gas has on the performance of pipeline steels, it is important to assess microstructures relevant to the welds present, as testing only on base metal may not provide conservative information. However, the results from well-planned and carefully executed programs can be used to identify the relative performance in hydrogen. The data can also be used as critical input to models which form part of an integrated approach to structural integrity assessment.