Van Hove Singularities, Superconductivity, and the Josephson Diode Effect in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>NiTe</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>2</mml:mn> <

Superconductivity in the transition-metal dichalcogenide PdTe_{2} has been attributed to the proximity of a three-dimensional Van Hove singularity to the Fermi level. In isostructural NiTe_{2}, recently used as the weak link in a Josephson diode, a similar Van Hove singularity has been predicted to occur, but superconductivity is mysteriously absent. Using bulk-sensitive soft x-ray angle-resolved photoemission spectroscopy, we reveal that this Van Hove singularity lies even closer to the Fermi level in NiTe_{2} than in PdTe_{2}. To explain the lack of superconductivity in NiTe_{2}, we perform ab initio calculations incorporating the Kukkonen Overhauser interaction, showing that an incipient magnetic instability suppresses superconductivity at an unprecedented scale. Finally, we present a tight-binding model that links the Van Hove singularity to a sign change in the Josephson diode effect at small magnetic fields, suggesting a new mechanism for Josephson diodes.

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Journal
Physical Review Letters
Published
2026-01-14
DOI
https://doi.org/10.1103/hp1t-zd7y
Primary Topic
Iron-based superconductors research
Type
article
Field-Weighted Citation Impact
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Van Hove Singularities, Superconductivity, and the Josephson Diode Effect in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>NiTe</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>2</mml:mn> <

Procopios Constantinou, Vladimir N. Strocov, Camilla Pellegrini, Mihir Date et al.
Physical Review Letters
Iron-based superconductors research
article

Van Hove Singularities, Superconductivity, and the Josephson Diode Effect in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>NiTe</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>2</mml:mn> <

Procopios Constantinou, Vladimir N. Strocov, Camilla Pellegrini, Mihir Date, Anna Hartl, Matthew J. Gilbert, Jonas A. Krieger, Banabir Pal, Gabriele Domaine, Anirban Chakraborty, Anonymous, Antonio SANNA, Pranava K. Sivakumar, Enrico G. Della Valle, Stuart S. P. Parkin
article en

Abstract

Superconductivity in the transition-metal dichalcogenide PdTe_{2} has been attributed to the proximity of a three-dimensional Van Hove singularity to the Fermi level. In isostructural NiTe_{2}, recently used as the weak link in a Josephson diode, a similar Van Hove singularity has been predicted to occur, but superconductivity is mysteriously absent. Using bulk-sensitive soft x-ray angle-resolved photoemission spectroscopy, we reveal that this Van Hove singularity lies even closer to the Fermi level in NiTe_{2} than in PdTe_{2}. To explain the lack of superconductivity in NiTe_{2}, we perform ab initio calculations incorporating the Kukkonen Overhauser interaction, showing that an incipient magnetic instability suppresses superconductivity at an unprecedented scale. Finally, we present a tight-binding model that links the Van Hove singularity to a sign change in the Josephson diode effect at small magnetic fields, suggesting a new mechanism for Josephson diodes.

Physical Review LettersVol. 136(8)
OTH Regensburg (DE), Max Planck Society (DE), University of Illinois System (US), Paul Scherrer Institute (CH), Diamond Light Source (GB), Swiss Light Source, Martin Luther University Halle-Wittenberg (DE)
Openalex Percentile: Top 88%
Iron-based superconductors research
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