Van Hove Singularities, Superconductivity, and the Josephson Diode Effect in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mi>NiTe</mml:mi> </mml:mrow> <mml:mrow> <mml:mn>2</mml:mn> <
Superconductivity in the transition-metal dichalcogenide PdTe_{2} has been attributed to the proximity of a three-dimensional Van Hove singularity to the Fermi level. In isostructural NiTe_{2}, recently used as the weak link in a Josephson diode, a similar Van Hove singularity has been predicted to occur, but superconductivity is mysteriously absent. Using bulk-sensitive soft x-ray angle-resolved photoemission spectroscopy, we reveal that this Van Hove singularity lies even closer to the Fermi level in NiTe_{2} than in PdTe_{2}. To explain the lack of superconductivity in NiTe_{2}, we perform ab initio calculations incorporating the Kukkonen Overhauser interaction, showing that an incipient magnetic instability suppresses superconductivity at an unprecedented scale. Finally, we present a tight-binding model that links the Van Hove singularity to a sign change in the Josephson diode effect at small magnetic fields, suggesting a new mechanism for Josephson diodes.
Authors
- Procopios Constantinou (ORCID: https://orcid.org/0000-0001-9769-9345)
- Vladimir N. Strocov (ORCID: https://orcid.org/0000-0002-1147-8486)
- Camilla Pellegrini (ORCID: https://orcid.org/0000-0003-2614-1111)
- Mihir Date (ORCID: https://orcid.org/0000-0002-9778-6104)
- Anna Hartl (ORCID: https://orcid.org/0000-0002-8615-2755)
- Matthew J. Gilbert (ORCID: https://orcid.org/0000-0001-9456-9545)
- Jonas A. Krieger (ORCID: https://orcid.org/0000-0003-3337-5530)
- Banabir Pal
- Gabriele Domaine (ORCID: https://orcid.org/0000-0002-8121-3547)
- Anirban Chakraborty
- Anonymous
- Antonio SANNA
- Pranava K. Sivakumar
- Enrico G. Della Valle
- Stuart S. P. Parkin
Institutions
- OTH Regensburg (DE)
- Max Planck Society (DE)
- University of Illinois System (US)
- Paul Scherrer Institute (CH)
- Diamond Light Source (GB)
- Swiss Light Source
- Martin Luther University Halle-Wittenberg (DE)
Publication Details
- Journal
- Physical Review Letters
- Published
- 2026-01-14
- DOI
- https://doi.org/10.1103/hp1t-zd7y
- Primary Topic
- Iron-based superconductors research
- Type
- article
- Field-Weighted Citation Impact
- 0.00