Mineralized Remains as Adjacent Proxy for Radiocarbon Dating

Since the 1950s, radiocarbon dating of archeological remains has evolved significantly with the advent of new instruments, protocols, and redesigned concepts. Here, we show that the recovery of chronological information "stored" locally can be achieved by the selective dating of carbonates present in adjacent mineralized organic materials. We present results from the iconic Iron Age site of Creney-le-Paradis (Aube, France). The <sup>14</sup>C ages extracted using an innovative selective strategy provide new evidence for the chronology of the foundation of the site. We show that the copper carbonate accretions retained the signature of an anthropogenic humus layer, accurately dated between 808 and 790 BC, allowing us to infer human activity associated with the foundation of the burial mound. This work opens the way for the development of spatially resolved dating imagery within sites, where the analysis of series of microsamples could document the chronology of their formation.

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Publication Details

Journal
Analytical Chemistry
Published
2026-01-14
DOI
https://doi.org/10.1021/acs.analchem.5c03812
Primary Topic
Archaeology and ancient environmental studies
Type
article
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article

Mineralized Remains as Adjacent Proxy for Radiocarbon Dating

Luc Robbiola, Elsa Desplanques, Clémence Iacconi, Laura Hendriks et al.
Analytical Chemistry
Archaeology and ancient environmental studies
article

Mineralized Remains as Adjacent Proxy for Radiocarbon Dating

Luc Robbiola, Elsa Desplanques, Clémence Iacconi, Laura Hendriks, C. Reynaud, Negar Haghipour, Loïc BERTRAND
article en

Abstract

Since the 1950s, radiocarbon dating of archeological remains has evolved significantly with the advent of new instruments, protocols, and redesigned concepts. Here, we show that the recovery of chronological information "stored" locally can be achieved by the selective dating of carbonates present in adjacent mineralized organic materials. We present results from the iconic Iron Age site of Creney-le-Paradis (Aube, France). The <sup>14</sup>C ages extracted using an innovative selective strategy provide new evidence for the chronology of the foundation of the site. We show that the copper carbonate accretions retained the signature of an anthropogenic humus layer, accurately dated between 808 and 790 BC, allowing us to infer human activity associated with the foundation of the burial mound. This work opens the way for the development of spatially resolved dating imagery within sites, where the analysis of series of microsamples could document the chronology of their formation.

Analytical ChemistryVol. 98(3)
Centre National de la Recherche Scientifique (FR), Université Paris-Saclay (FR), Sorbonne Université (FR), School of Engineering and Architecture of Fribourg (CH), HES-SO Fribourg (CH), Geological Institute (RU), Ion Beam Applications (France) (FR), Centre André-Chastel (FR), Université Toulouse - Jean Jaurès (FR)
Sustainable cities and communities
Openalex Percentile: Top 93%
Archaeology and ancient environmental studies
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Mineralized Remains as Adjacent Proxy for Radiocarbon Dating — Luc Robbiola, Elsa Desplanques, et al. · Analytical Chemistry (2026) | TGRS Research Map | TGRS