A Variational Formulation for Irreversible Thermodynamics with Path Dependence

This work introduces a path-dependent energy Lagrangian for irreversible thermomechanics that embeds heat and entropy accounting directly into the action. The formulation requires neither Lagrange multipliers nor Rayleigh potentials. An explicit θs term enforces Helmholtz conjugacy and positive heat capacity; writing heat as a divergence produces the natural flux; nonnegative dissipative productions are collected in a single modular term; and a history integral supplies an upper-limit variation that converts instantaneous power into entropy production. Stationarity yields the standard field equations together with a global entropy balance and a channel-wise power identity by placing each production once in entropy and once, with opposite sign, in its own channel. Classical closures-including Fourier and non-Fourier heat conduction, diffusion, and viscous mechanics-arise as special cases of the same functional. Compact examples show how the framework provides a unified action, a single entropy audit, and consistent positive production across coupled dissipative mechanisms.

Authors

Institutions

Publication Details

Journal
Entropy
Published
2026-01-13
DOI
https://doi.org/10.3390/e28010094
Primary Topic
Advanced Thermodynamics and Statistical Mechanics
Type
article
Field-Weighted Citation Impact
0.00
Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

A Variational Formulation for Irreversible Thermodynamics with Path Dependence

Huilong Ren
Entropy
Advanced Thermodynamics and Statistical Mechanics
article

A Variational Formulation for Irreversible Thermodynamics with Path Dependence

Huilong Ren
article en

Abstract

This work introduces a path-dependent energy Lagrangian for irreversible thermomechanics that embeds heat and entropy accounting directly into the action. The formulation requires neither Lagrange multipliers nor Rayleigh potentials. An explicit θs term enforces Helmholtz conjugacy and positive heat capacity; writing heat as a divergence produces the natural flux; nonnegative dissipative productions are collected in a single modular term; and a history integral supplies an upper-limit variation that converts instantaneous power into entropy production. Stationarity yields the standard field equations together with a global entropy balance and a channel-wise power identity by placing each production once in entropy and once, with opposite sign, in its own channel. Classical closures-including Fourier and non-Fourier heat conduction, diffusion, and viscous mechanics-arise as special cases of the same functional. Compact examples show how the framework provides a unified action, a single entropy audit, and consistent positive production across coupled dissipative mechanisms.

EntropyVol. 28(1)
Tongji University (CN)
Affordable and clean energy
Openalex Percentile: Top 88%
Advanced Thermodynamics and Statistical Mechanics
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.