Catalytic CO2 Utilization for Ethanol Reforming over Yttrium-Promoted Ni-Co/MCM-41 Catalyst: Optimizing Hydrogen Production Using Box–Behnken Experimental Design and Response Surface Methodology

Catalytic dry reforming of ethanol offers a sustainable pathway for syngas and hydrogen production through CO2 utilization, though its efficiency depends heavily on the strategic synthesis of catalysts and the optimization of reaction parameters. This study employs Box–Behnken Design (BBD) and Response Surface Methodology (RSM) to optimize hydrogen yield from CO2 reforming of ethanol over a Yttrium-promoted Ni-Co/MCM-41 catalyst. The catalyst was synthesized using sequential wet impregnation method and characterized for its physicochemical properties. The catalyst was tested in fixed-bed reactor using experimental data obtained from BBD considering the effects of temperature (550–700 °C), ethanol flowrate (0.5–1 mL/min) and CO2 flowrate (15–30 mL/min) on the hydrogen yield. The experimental conditions were optimized using RSM quadratic model. The characterization revealed that the ordered mesoporous nature of the MCM-41 is maintained providing a high surface area of 597.75 m2/g for the catalyst. The addition of Yttrium as a promoter facilitates the formation of well crystallized nanoparticles. Maximum hydrogen yield of 85.09% was obtained at 700 °C, 20.393 mL/min and 0.877 mL/min for temperature, CO2 and ethanol flowrate, respectively. The predicted hydrogen yield obtained is strongly correlated with the actual values as indicated by R2 of 0.9570.