The Effect of CO2 Laser Treatment on the Composition of Cotton/Polyester/Metal Fabric

The effect of CO₂ laser treatment on the surface composition and properties of a woven fabric (polyester (PET) fiber (59 wt%)/cotton (CO) fiber (31 wt%)/stainless-steel (SS) metal fibers (10 wt%)) was investigated across a range of laser intensities (19.1 × 10⁶ to 615.0 × 10⁶ W/m²). Elemental analysis using wavelength-dispersive X-ray fluorescence (WD-XRF) revealed that for an intensity up to 225.4 × 10⁶ W/m², the carbon content on the fabric surface increased while the oxygen content decreased, indicating thermally induced surface modification. Fourier transform infrared (FT-IR) spectroscopy confirmed that no new chemical bonds were formed, suggesting that the changes observed were predominantly physical in nature. High-resolution scanning electron microscopy (HR-SEM) showed progressive fiber fusion and surface smoothing with increasing laser intensity, consistent with polyester melting. Tensile testing demonstrated a significant decline in peak load and elongation at peak load with rising laser fluence, indicating mechanical embrittlement. Overall, CO₂ laser treatment alters the morphology and elemental composition of the fabric surface without inducing major chemical decomposition, markedly reducing its mechanical strength.