Evaluation of the Impact of Submerged Zone Height on the Performance of Iron-Carbon Bioretention System

Traditional bioretention systems have limited nitrogen and phosphorus removal capacity and insufficient operational stability. To address this issue, this study developed an iron-carbon bioretention system (IB) with varying submerged zone heights. The system’s performance in removing pollutants was systematically evaluated under different rainfall intensities, influent pollutant concentrations, and antecedent drying durations. In addition, the potential nitrification ability (PNA) of the substrate, denitrifying enzyme activity (DEA), and phosphorus species were analyzed to reveal the mechanisms responsible for its efficient nitrogen and phosphorus removal. The results showed that a submerged zone height of 400 mm enabled the IB system to achieve removal rates of 98.05% for NO3−-N and 91.67% for total nitrogen (TN). The removal rates of total phosphorus (TP) and chemical oxygen demand (COD) remained stable at over 91% and 92%, respectively. The submerged zone also created a stable anoxic environment, while the iron-carbon micro-electrolysis process continually consumed dissolved oxygen and provided Fe2+ as an electron donor, enhancing both the denitrification process and chemical phosphorus removal. Furthermore, the IB system demonstrated superior stability when dealing with high hydraulic and pollutant loads, as well as varying dry periods, with the effluent iron concentration maintained at low levels. This study confirms that iron-carbon micro-electrolysis and the incorporation of a submerged zone can significantly enhance the removal performance of bioretention systems, offering a reference for addressing nitrogen and phosphorus pollution in urban stormwater runoff.