Defective TiO <sub> <i>x</i> </sub> spontaneously triggers the hydrogenation activity of silver
The reactive metal-support interaction (RMSI) between Ag and defective TiO<sub><i>x</i></sub> spontaneously triggers the selective silver-catalyzed hydrogenation of dimethyl oxalate to methyl glycolate, enabling a >5-fold increase in TOF without prereduction. Importantly, TiO<sub><i>x</i></sub> confers remarkable oxidation resistance to the metallic Ag phase.
Authors
- Zuo‐Chang Chen (ORCID: https://orcid.org/0000-0001-5201-0524)
- Linmin Ye (ORCID: https://orcid.org/0000-0003-0721-2287)
- Duan Xinping
- Haiqiang Lin
- Youzhu Yuan
- Jianwei Zheng
- Wei Zhao
Institutions
- Xiamen University (CN)
- Collaborative Innovation Center of Chemistry for Energy Materials (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2026-01-01
- DOI
- https://doi.org/10.1039/d5cc06528c
- Primary Topic
- Catalysis for Biomass Conversion
- Type
- article
- Field-Weighted Citation Impact
- 0.00