Effect of immobilized amine structure on the formation and catalysis of Pd nanoparticles for oxidation of alcohols

Silica supports with various types of immobilized amines were systematically prepared and the effect of the amine structures on the formation and catalysis of Pd nanoparticles was studied. Tertiary amino groups were found to be suitable for forming monodisperse and active Pd nanoparticles while suppressing the side reaction during the alcohol oxidation.

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Publication Details

Journal
Chemical Communications
Published
2026-01-01
DOI
https://doi.org/10.1039/d5cc06272a
Primary Topic
Oxidative Organic Chemistry Reactions
Type
article
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article

Effect of immobilized amine structure on the formation and catalysis of Pd nanoparticles for oxidation of alcohols

Ken Motokura, Runa Kobayashi, Shingo Hasegawa, Meiji Honda et al.
Chemical Communications
Oxidative Organic Chemistry Reactions
article

Effect of immobilized amine structure on the formation and catalysis of Pd nanoparticles for oxidation of alcohols

Ken Motokura, Runa Kobayashi, Shingo Hasegawa, Meiji Honda, Shinji Tanaka
article en

Abstract

Silica supports with various types of immobilized amines were systematically prepared and the effect of the amine structures on the formation and catalysis of Pd nanoparticles was studied. Tertiary amino groups were found to be suitable for forming monodisperse and active Pd nanoparticles while suppressing the side reaction during the alcohol oxidation.

Chemical CommunicationsVol. 62(8)
Yokohama National University (JP), National Institute of Advanced Industrial Science and Technology (JP)
Clean water and sanitation
Openalex Percentile: Top 91%
Oxidative Organic Chemistry Reactions
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