Bis(cyclooctadiene)nickel(0)-catalyzed exhaustive C(sp <sup>2</sup> )–X and C(sp <sup>3</sup> )–F hydrodehalogenation and deuterodefluorination of pyridines and arenes with a broad substrate scope

The exhaustive HDH and DDH of CF 3 groups in pyridines and the HDH of C(sp 2 )–X (X = F, Cl, Br, and I) bonds in pyridines and arenes were catalyzed by [Ni(COD) 2 ] using NH 3 BH 3 (for HDH) or ND 3 BD 3 (for DDH) and KO t Bu at room temperature.

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Publication Details

Journal
Inorganic Chemistry Frontiers
Published
2026-01-01
DOI
https://doi.org/10.1039/d6qi00010j
Primary Topic
Fluorine in Organic Chemistry
Type
article
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article

Bis(cyclooctadiene)nickel(0)-catalyzed exhaustive C(sp 2 )–X and C(sp 3 )–F hydrodehalogenation and deuterodefluorination of pyridines and arenes with a broad substrate scope

Himani Ahuja, Rebeca Arevalo
Inorganic Chemistry Frontiers
Fluorine in Organic Chemistry
article

Bis(cyclooctadiene)nickel(0)-catalyzed exhaustive C(sp 2 )–X and C(sp 3 )–F hydrodehalogenation and deuterodefluorination of pyridines and arenes with a broad substrate scope

Himani Ahuja, Rebeca Arevalo
article en

Abstract

The exhaustive HDH and DDH of CF 3 groups in pyridines and the HDH of C(sp 2 )–X (X = F, Cl, Br, and I) bonds in pyridines and arenes were catalyzed by [Ni(COD) 2 ] using NH 3 BH 3 (for HDH) or ND 3 BD 3 (for DDH) and KO t Bu at room temperature.

Inorganic Chemistry Frontiers
University of California, Merced (US)
Openalex Percentile: Top 91%
Fluorine in Organic Chemistry
DOISourceOpenAlex
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Bis(cyclooctadiene)nickel(0)-catalyzed exhaustive C(sp <sup>2</sup> )–X and C(sp <sup>3</sup> )–F hydrodehalogenation and deuterodefluorination of pyridines and arenes with a broad substrate scope — Himani Ahuja, Rebeca Arevalo · Inorganic Chemistry Frontiers (2026) | TGRS Research Map | TGRS