Synthesis and Structures of Organogold 4,4,5,5-Tetramethyl-4,5-Dihydroimidazole-3-Oxide-1-Oxyl Derivatives Stabilized by Phosphine Ligands

Organogold derivatives of nitronyl nitroxide, stabilized by phosphine ligands are obtained. Conformational features of the phosphine ligands and nitronyl nitroxide nuclei are analyzed by single crystal X-ray diffraction. Effective π–π stacking interactions are detected and described for the first time in the crystals of organogold derivatives.

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Journal
Journal of Structural Chemistry
Published
2025-12-01
DOI
https://doi.org/10.1134/s0022476625120170
Primary Topic
Crystal structures of chemical compounds
Type
article
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article

Synthesis and Structures of Organogold 4,4,5,5-Tetramethyl-4,5-Dihydroimidazole-3-Oxide-1-Oxyl Derivatives Stabilized by Phosphine Ligands

D. I. Nasyrova, P. G. Shangin, E. V. Tretyakov, M. A. Syroeshkin et al.
Journal of Structural Chemistry
Crystal structures of chemical compounds
article

Synthesis and Structures of Organogold 4,4,5,5-Tetramethyl-4,5-Dihydroimidazole-3-Oxide-1-Oxyl Derivatives Stabilized by Phosphine Ligands

D. I. Nasyrova, P. G. Shangin, E. V. Tretyakov, M. A. Syroeshkin, A. A. Korlyukov, I. Yu. Bagryanskaya, I. A. Zayakin, M. E. Minyaev
article en

Abstract

Organogold derivatives of nitronyl nitroxide, stabilized by phosphine ligands are obtained. Conformational features of the phosphine ligands and nitronyl nitroxide nuclei are analyzed by single crystal X-ray diffraction. Effective π–π stacking interactions are detected and described for the first time in the crystals of organogold derivatives.

Journal of Structural ChemistryVol. 66(12)
A. N. Nesmeyanov Institute of Organoelement Compounds (RU), N.D. Zelinsky Institute of Organic Chemistry (RU), Novosibirsk Institute of Organic Chemistry (RU)
Clean water and sanitation
Openalex Percentile: Top 43%
Crystal structures of chemical compounds
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