Polymorphism of Crystal Structures of the [Cu2(S–C6F4–CF3)2(dmap)4] Complex

The structure of the [Cu2(S–C6F4–CF3)2(dmap)4] (dmap - 4-dimethylaminopyridine) complex is determined by single crystal X-ray diffraction (XRD). It is found that when cooled below 230 K, the complex undergoes a phase transition forming another polymorph that is also characterized by single crystal XRD.

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Publication Details

Journal
Journal of Structural Chemistry
Published
2025-12-01
DOI
https://doi.org/10.1134/s0022476625120078
Primary Topic
Organometallic Compounds Synthesis and Characterization
Type
article
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article

Polymorphism of Crystal Structures of the [Cu2(S–C6F4–CF3)2(dmap)4] Complex

P. A. Petrov, P. A. Abramov, I. V. Korolkov, A. M. Maksimov et al.
Journal of Structural Chemistry
Organometallic Compounds Synthesis and Characterization
article

Polymorphism of Crystal Structures of the [Cu2(S–C6F4–CF3)2(dmap)4] Complex

P. A. Petrov, P. A. Abramov, I. V. Korolkov, A. M. Maksimov, E. A. Filippova, T. S. Sukhikh, M. N. Sokolov
article en

Abstract

The structure of the [Cu2(S–C6F4–CF3)2(dmap)4] (dmap - 4-dimethylaminopyridine) complex is determined by single crystal X-ray diffraction (XRD). It is found that when cooled below 230 K, the complex undergoes a phase transition forming another polymorph that is also characterized by single crystal XRD.

Journal of Structural ChemistryVol. 66(12)
Novosibirsk Institute of Organic Chemistry (RU), Nikolaev Institute of Inorganic Chemistry (RU)
Openalex Percentile: Top 32%
Organometallic Compounds Synthesis and Characterization
DOISourceOpenAlex
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Polymorphism of Crystal Structures of the [Cu2(S–C6F4–CF3)2(dmap)4] Complex — P. A. Petrov, P. A. Abramov, et al. · Journal of Structural Chemistry (2025) | TGRS Research Map | TGRS