Cavity Controls Core-to-Core Resonant Inelastic X-Ray Scattering

X-ray cavity quantum optics with inner-shell transitions has been limited by the spectral overlap between resonant and continuum states. Here, we report the first experimental demonstration of cavity-controlled core-to-core resonant inelastic x-ray scattering (RIXS). We suppress the absorption-edge effects by monitoring the RIXS profile, thereby resolving the resonant state from the overlapping continuum. We observe distinct cavity-induced energy shifts and cavity-enhanced decay rates in the 2p3d RIXS spectra of WSi_{2}. These effects, manifesting as stretched or shifted profiles in the RIXS planes, enable novel spectroscopic applications via cavity-controlled core-hole states. Our results establish core-to-core RIXS as a powerful tool to manipulate inner-shell dynamics in x-ray cavities, offering new avenues for integrating quantum optical effects with x-ray spectroscopy.

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Publication Details

Journal
Physical Review Letters
Published
2026-01-09
DOI
https://doi.org/10.1103/z6xz-p7cm
Primary Topic
Crystallography and Radiation Phenomena
Type
article
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article

Cavity Controls Core-to-Core Resonant Inelastic X-Ray Scattering

J.-P Rueff, W. B. Li, T. P. Li, L-F Zhu et al.
Physical Review Letters
Crystallography and Radiation Phenomena
article

Cavity Controls Core-to-Core Resonant Inelastic X-Ray Scattering

J.-P Rueff, W. B. Li, T. P. Li, L-F Zhu, T. Hu, Z-Q Zhao, Anonymous, A. Khadiev, F. Alves Lima, B.-H. Wang, X.-Y. Wang, H.-C. Wang, Y. Uemura, Y. Su, O. J. L. Fox, J. M. Ablett
article en

Abstract

X-ray cavity quantum optics with inner-shell transitions has been limited by the spectral overlap between resonant and continuum states. Here, we report the first experimental demonstration of cavity-controlled core-to-core resonant inelastic x-ray scattering (RIXS). We suppress the absorption-edge effects by monitoring the RIXS profile, thereby resolving the resonant state from the overlapping continuum. We observe distinct cavity-induced energy shifts and cavity-enhanced decay rates in the 2p3d RIXS spectra of WSi_{2}. These effects, manifesting as stretched or shifted profiles in the RIXS planes, enable novel spectroscopic applications via cavity-controlled core-hole states. Our results establish core-to-core RIXS as a powerful tool to manipulate inner-shell dynamics in x-ray cavities, offering new avenues for integrating quantum optical effects with x-ray spectroscopy.

Physical Review LettersVol. 136(6)
Tongji University (CN), University of Science and Technology of China (CN), GSI Helmholtz Centre for Heavy Ion Research (DE), Synchrotron soleil (FR), Deutsches Elektronen-Synchrotron DESY (DE), Diamond Light Source (GB), Sorbonne Université (FR), Laboratoire de Chimie Physique - Matière et Rayonnement (FR), Laboratoire Médiations (FR), European X-Ray Free-Electron Laser (DE)
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Crystallography and Radiation Phenomena
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