Terephthalic acid intercalation strengthens NiFe-layered double hydroxide for durable and efficient seawater electrolysis

A terephthalic-acid intercalation strategy reinforces NiFe-LDH through C-O-Fe coordination, expanding interlayer spacing and optimizing charge transfer. The resulting NiFe-LDH(TPA) achieves 216 mV at 10 mA cm<sup>-2</sup> and 700 h durability in alkaline seawater, outperforming RuO<sub>2</sub>. This molecular approach simultaneously enhances activity, stability, and corrosion resistance for seawater electrolysis.

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Publication Details

Journal
Chemical Communications
Published
2026-01-01
DOI
https://doi.org/10.1039/d5cc06658a
Primary Topic
Electrocatalysts for Energy Conversion
Type
article
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article

Terephthalic acid intercalation strengthens NiFe-layered double hydroxide for durable and efficient seawater electrolysis

Yaohai Cai, Zhenbo Wang, Xinghong Li, D. L. Zhu et al.
Chemical Communications
Electrocatalysts for Energy Conversion
article

Terephthalic acid intercalation strengthens NiFe-layered double hydroxide for durable and efficient seawater electrolysis

Yaohai Cai, Zhenbo Wang, Xinghong Li, D. L. Zhu, Lei Wang, Kai Liu, Yuxin Zhu, Dong Liu, Yi Huang
article en

Abstract

A terephthalic-acid intercalation strategy reinforces NiFe-LDH through C-O-Fe coordination, expanding interlayer spacing and optimizing charge transfer. The resulting NiFe-LDH(TPA) achieves 216 mV at 10 mA cm<sup>-2</sup> and 700 h durability in alkaline seawater, outperforming RuO<sub>2</sub>. This molecular approach simultaneously enhances activity, stability, and corrosion resistance for seawater electrolysis.

Chemical CommunicationsVol. 62(10)
Shenzhen University (CN), Harbin Institute of Technology (CN), Shenzhen Technology University (CN), Guangdong Institute of New Materials (CN)
Openalex Percentile: Top 93%
Electrocatalysts for Energy Conversion
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