Controllable self-assembly of a <i>mesomeric</i> metallo-organic helicate and its π-electron number dependent encapsulation of polycyclic aromatic hydrocarbons (PAHs)

A mesomeric helicate has been obtained by modulating metal centers’ handedness. It can recognize PAHs, and the binding affinity increases proportionally with the number of PAHs' π electrons, acting as an efficient method to enhance binding affinity.

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Publication Details

Journal
Inorganic Chemistry Frontiers
Published
2026-01-01
DOI
https://doi.org/10.1039/d5qi02447a
Primary Topic
Supramolecular Self-Assembly in Materials
Type
article
Field-Weighted Citation Impact
0.00
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article

Controllable self-assembly of a mesomeric metallo-organic helicate and its π-electron number dependent encapsulation of polycyclic aromatic hydrocarbons (PAHs)

Qixia Bai, Tun Wu, Pingshan Wang, Zhe Zhang et al.
Inorganic Chemistry Frontiers
Supramolecular Self-Assembly in Materials
article

Controllable self-assembly of a mesomeric metallo-organic helicate and its π-electron number dependent encapsulation of polycyclic aromatic hydrocarbons (PAHs)

Qixia Bai, Tun Wu, Pingshan Wang, Zhe Zhang, Tian-Yu Liu, Qingwu Long, huoqing Chen, Yuming Guan, Tian Li, Haoxuan Xu
article en

Abstract

A mesomeric helicate has been obtained by modulating metal centers’ handedness. It can recognize PAHs, and the binding affinity increases proportionally with the number of PAHs' π electrons, acting as an efficient method to enhance binding affinity.

Inorganic Chemistry Frontiers
Taiyuan Normal University (CN), Guangzhou University (CN), China Design Group (China) (CN), Shunde Polytechnic (CN), Pearl River Hydraulic Research Institute (CN)
Openalex Percentile: Top 94%
Supramolecular Self-Assembly in Materials
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