Synthesis, crystal structure, and Hirshfeld surface analysis of bis{2-[( <i>E</i> )-( <i>p</i> -tolylimino)methyl]benzen-1-olato}palladium
The title compound, [Pd(C<sub>14</sub>H<sub>12</sub>NO)<sub>2</sub>], contains an <i>N,O</i>-bidentate ligand and features a square-planar Pd<sup>II</sup> atom coordinated to two chelating ligands. Each ligand binds through one nitro-gen atom and one oxygen donor atom, forming two six-membered chelate rings. The Pd<sup>II</sup> atom lies essentially within the coordination plane, with the <i>trans</i> arrangement of the donor atoms giving rise to the square-planar geometry. In the crystal, the mol-ecules are linked through weak C-H⋯π inter-actions, which direct the mol-ecular packing. To gain further insights into the inter-molecular contacts, a Hirshfeld surface analysis was performed.
Authors
- Siti Syaida Sirat (ORCID: https://orcid.org/0000-0001-6103-7710)
- Amalina Mohd Tajuddin (ORCID: https://orcid.org/0000-0003-2167-1383)
- Mohd Mustaqim Rosli (ORCID: https://orcid.org/0000-0001-8402-1914)
- Nur Nabihah Muzammil
- Mohd Tajudin Mohd Ali
- Muhamad Azwan Hamali
Institutions
- Universiti Sains Malaysia (MY)
- Universiti Teknologi MARA System (MY)
- Universiti Teknologi MARA (MY)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2026-01-02
- DOI
- https://doi.org/10.1107/s2056989025011570
- Primary Topic
- Synthesis and characterization of novel inorganic/organometallic compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00