Synthesis, crystal structure, and Hirshfeld surface analysis of bis{2-[( <i>E</i> )-( <i>p</i> -tolylimino)methyl]benzen-1-olato}palladium

The title compound, [Pd(C<sub>14</sub>H<sub>12</sub>NO)<sub>2</sub>], contains an <i>N,O</i>-bidentate ligand and features a square-planar Pd<sup>II</sup> atom coordinated to two chelating ligands. Each ligand binds through one nitro-gen atom and one oxygen donor atom, forming two six-membered chelate rings. The Pd<sup>II</sup> atom lies essentially within the coordination plane, with the <i>trans</i> arrangement of the donor atoms giving rise to the square-planar geometry. In the crystal, the mol-ecules are linked through weak C-H⋯π inter-actions, which direct the mol-ecular packing. To gain further insights into the inter-molecular contacts, a Hirshfeld surface analysis was performed.

Authors

Institutions

Publication Details

Journal
Acta Crystallographica Section E Crystallographic Communications
Published
2026-01-02
DOI
https://doi.org/10.1107/s2056989025011570
Primary Topic
Synthesis and characterization of novel inorganic/organometallic compounds
Type
article
Field-Weighted Citation Impact
0.00
Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Synthesis, crystal structure, and Hirshfeld surface analysis of bis{2-[( E )-( p -tolylimino)methyl]benzen-1-olato}palladium

Siti Syaida Sirat, Amalina Mohd Tajuddin, Mohd Mustaqim Rosli, Nur Nabihah Muzammil et al.
Acta Crystallographica Section E Crystallographic Communications
Synthesis and characterization of novel inorganic/organometallic compounds
article

Synthesis, crystal structure, and Hirshfeld surface analysis of bis{2-[( E )-( p -tolylimino)methyl]benzen-1-olato}palladium

Siti Syaida Sirat, Amalina Mohd Tajuddin, Mohd Mustaqim Rosli, Nur Nabihah Muzammil, Mohd Tajudin Mohd Ali, Muhamad Azwan Hamali
article en

Abstract

The title compound, [Pd(C<sub>14</sub>H<sub>12</sub>NO)<sub>2</sub>], contains an <i>N,O</i>-bidentate ligand and features a square-planar Pd<sup>II</sup> atom coordinated to two chelating ligands. Each ligand binds through one nitro-gen atom and one oxygen donor atom, forming two six-membered chelate rings. The Pd<sup>II</sup> atom lies essentially within the coordination plane, with the <i>trans</i> arrangement of the donor atoms giving rise to the square-planar geometry. In the crystal, the mol-ecules are linked through weak C-H⋯π inter-actions, which direct the mol-ecular packing. To gain further insights into the inter-molecular contacts, a Hirshfeld surface analysis was performed.

Acta Crystallographica Section E Crystallographic CommunicationsVol. 82(2)
Universiti Sains Malaysia (MY), Universiti Teknologi MARA System (MY), Universiti Teknologi MARA (MY)
Openalex Percentile: Top 94%
Synthesis and characterization of novel inorganic/organometallic compounds
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.

Synthesis, crystal structure, and Hirshfeld surface analysis of bis{2-[( <i>E</i> )-( <i>p</i> -tolylimino)methyl]benzen-1-olato}palladium — Siti Syaida Sirat, Amalina Mohd Tajuddin, et al. · Acta Crystallographica Section E Crystallographic Communications (2026) | TGRS Research Map | TGRS